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La ricerca find articoli where soggetti phrase all words 'cyclobutadiene' sort by level,fasc_key/DESCEND, pagina_ini_num/ASCEND ha restituito 181 riferimenti
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    1. Lo, PCK; Snapper, ML
      Intramolecular [2+2]-photocycloaddition/thermal fragmentation approach toward 5-8-5 ring systems

      ORGANIC LETTERS
    2. Wong, WY; Lu, GL; Ng, KF; Choi, KH; Lin, ZY
      Synthesis, structures and properties of platinum( II) complexes of oligothiophene-functionalized ferrocenylacetylene

      JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
    3. Warmuth, R
      Inner-phase stabilization of reactive intermediates

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    4. Laskoski, M; Roidl, G; Smith, MD; Bunz, UHF
      Concave butterfly-shaped organometallic hydrocarbons?

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    5. Laskoski, M; Steffen, W; Smith, MD; Bunz, UHF
      Is ferrocene more aromatic than benzene?

      CHEMICAL COMMUNICATIONS
    6. Sekiguchi, A; Matsuo, T; Watanabe, H
      Cyclobutadiene dianion dilithium: a new aromatic ring system

      PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
    7. Notario, R; Castano, O; Andres, JL; Elguero, J; Maier, G; Hermann, C
      An experimental and theoretical study of the basicity of tetra-tert-butyltetrahedrane

      CHEMISTRY-A EUROPEAN JOURNAL
    8. Stanger, A; Tkachenko, E
      Strain induced bond localization in strained aromatic compounds with extended pi systems

      JOURNAL OF COMPUTATIONAL CHEMISTRY
    9. Ohkita, M; Sano, K; Suzuki, T; Tsuji, T
      Experimental and computational studies of naphtho[2,3-c]tropone: a highly polarized novel troponid system

      TETRAHEDRON LETTERS
    10. Roers, R; Hofmann, J; Classen, J; Gleiter, R
      Synthesis of a superphane dimer-a metallocenophane with four metal centers

      TETRAHEDRON LETTERS
    11. Kilic, H; Balci, M
      A new antiaromatic compound: 1,4-biphenylenequinone synthesis and trappingreactions: can a quinone unit stabilize the cyclobutadiene?

      TETRAHEDRON
    12. Smith, DM; Baric, D; Maksic, ZB
      On the correlation energy features in planar heteroatomic molecular systems

      JOURNAL OF CHEMICAL PHYSICS
    13. Shiota, Y; Kondo, M; Yoshizawa, K
      Role of molecular distortions in the spin-orbit coupling between the singlet and triplet states of the 4 pi electron systems C4H4, C5H5+, and C3H3-

      JOURNAL OF CHEMICAL PHYSICS
    14. Schaad, LJ; Hess, BA
      Dewar resonance energy

      CHEMICAL REVIEWS
    15. Bersuker, IB
      Modern aspects of the Jahn-Teller effect theory and applications to molecular problems

      CHEMICAL REVIEWS
    16. Warner, PM; Jones, GB
      Butalene and related compounds: Aromatic or antiaromatic?

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    17. Rohmer, MM; Strich, A; Benard, M; Malrieu, JP
      Metal-metal bond length variability in Co-3(dipyridylamide)(4)Cl-2: Bond-stretch isomerism, crystal field effects, or spin transition process? A DFT study

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    18. Deak, HL; Stokes, SS; Snapper, ML
      New approach to bicycle [5.3.0] ring systems

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    19. Yamanishi, H; Tomita, I; Ohta, K; Endo, T
      Solid dimorphism of tetra-arylcyclobutadienecobalt derivatives bearing long aliphatic lateral groups

      MOLECULAR CRYSTALS AND LIQUID CRYSTALS
    20. Milburn, RK; Bohme, DK; Hopkinson, AC
      Small-ring carbenes carrying a positive charge: the effects of substituting by CN in c-C4H3+

      INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
    21. Maksic, ZB; Baric, D; Petanjek, I
      On the correlation energy of pi-electrons in planar hydrocarbons

      JOURNAL OF PHYSICAL CHEMISTRY A
    22. Redington, RL
      Ab initio modeled matrix trapping sites, PES asymmetry, and automerizationin the Ar/cyclobutadiene system

      JOURNAL OF PHYSICAL CHEMISTRY A
    23. Wrobel, R; Sander, W; Cremer, D; Kraka, E
      Photochemistry of butatriene - Spectroscopic evidence for the existence ofallenylcarbene

      JOURNAL OF PHYSICAL CHEMISTRY A
    24. Matsuo, T; Mizue, T; Sekiguchi, A
      Synthesis and molecular structure of a dilithium salt of the cis-diphenylcyclobutadiene dianion

      CHEMISTRY LETTERS
    25. Yu, ZH; Xuan, ZQ
      The destabilization of pi-electron delocalization in cyclopentadiene - A method of separating out of its pi, pi-like and sigma fragment molecular orbitals

      CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
    26. Jursic, BS
      Computing the heat of formation for cubane and tetrahedrane with density functional theory and complete basis set ab initio methods

      JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM
    27. Hess, BA; Schaad, LJ
      Density functional theory and the computation of vibrational spectra of reactive organic species

      MOLECULAR PHYSICS
    28. Bunz, UHF; Roidl, G; Adams, RD
      A novel weakly diatropic dehydroannulene containing the cyclobutadiene(cyclopentadienyl)cobalt unit. An organometallic dehydroannulene that obeys Huckel's rule

      JOURNAL OF ORGANOMETALLIC CHEMISTRY
    29. Broadus, KM; Kass, SR
      Benzocyclobutadienyl anion: Formation and energetics of an antiaromatic molecule

      JOURNAL OF ORGANIC CHEMISTRY
    30. Smith, JR; Lemal, DM
      Synthetic approaches to a fluorinated tetrahedrane

      JOURNAL OF FLUORINE CHEMISTRY
    31. Belanzoni, P; Sgamellotti, A; Re, N; Floriani, C
      Oligomerization of early transition metal {M(OH)(3)}(2)(mu-C-2) acetylidestoward the formation of [(OH)(3)MC](n) (n=4,6) metalla carbides: A theoretical study by density functional theory

      INORGANIC CHEMISTRY
    32. Dias, JR
      Strongly subspectral series containing the cyclobutadiene moiety

      CROATICA CHEMICA ACTA
    33. Priyakumar, UD; Sastry, GN
      Structures, energetics, relative stabilities, and out-of-plane distortivities of skeletally disubstituted benzenes, (CH)(4)X-2 (X = N, P, C-, Si-, O+, and S+): An ab initio and DFT study

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    34. Broadus, KM; Kass, SR
      The electron as a protecting group. 2. Generation of benzocyclobutadiene radical anion in the gas phase and an experimental determination of the heatof formation of benzocyclobutadiene

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    35. Qian, WY; Bartberger, MD; Pastor, SJ; Houk, KN; Wilkins, CL; Rubin, Y
      C-62, a non-classical fullerene incorporating a four-membered ring

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    36. Beckhaus, HD; Faust, R; Matzger, AJ; Mohler, DL; Rogers, DW; Ruchardt, C; Sawhney, AK; Verevkin, SP; Vollhardt, KPC; Wolff, S
      The heat of hydrogenation of (a) cyclohexatriene

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    37. Zabka, J; Dolejsek, Z; Hrusak, J; Herman, Z
      A crossed beam scattering study of reactions in the system acetylene cation-acetylene: formation of C2HD+center dot in C2D2+center dot+C2H2 and formation of C4H3+ and C4H2+center dot in C2H2+center dot+C2H2 collisions

      INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
    38. Barckholtz, TA; Miller, TA
      The calculation of spectroscopic Jahn-Teller parameters by ab initio methods

      JOURNAL OF PHYSICAL CHEMISTRY A
    39. Lawson, DB; DeKock, RL
      Geometry and electronic structure of titanacycloalkenes

      JOURNAL OF PHYSICAL CHEMISTRY A
    40. Kudoh, S; Takayanagi, M; Nakata, M
      Dewar pyridine studied by matrix isolation infrared spectroscopy and DFT calculation

      JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
    41. Zilberg, S; Haas, Y
      Molecular photochemistry: A general method for localizing conical intersections using the phase-change rule

      CHEMISTRY-A EUROPEAN JOURNAL
    42. Bunz, UHF
      Carbon-rich molecular objects from multiply ethynylated pi-complexes

      CARBON RICH COMPOUNDS II
    43. Bunz, UHF; Rubin, Y; Tobe, Y
      Polyethynylated cyclic pi-systems: scaffoldings for novel two and three-dimensional carbon networks

      CHEMICAL SOCIETY REVIEWS
    44. Kato, T; Yoshizawa, K; Yamabe, T
      Vibronic coupling and Jahn-Teller effects in negatively charged [30]annulene

      CHEMICAL PHYSICS
    45. Jaworska, M
      RHF, UHF, CASSCF and CASPT2 calculations for (cyclobutadiene)tricarbonyliron, CbFe(CO)(3)

      CHEMICAL PHYSICS
    46. Sawada, Y; Tomita, I; Endo, T
      Synthesis of novel organocobalt poly(arylene-vinylene)s containing (cyclobutadiene)cobalt moieties in the main chain

      POLYMER BULLETIN
    47. Jursic, BS
      Exploring the lowest energy triplet potential energy surface for cyclic C4H4 isomers with the complete basis set ab initio method. Is the transformation of triafulvene into cyclobutadiene possible in their excited states?

      JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM
    48. Salcedo, R; Olvera, C
      Aromatic behavior of three membered rings

      THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE
    49. Porter, JR; Snapper, ML
      Formation of carbon-carbon bonds using iron tricarbonyl(eta(4)-cyclobutadienyl)-stabilized carbonium ions

      SYNTHESIS-STUTTGART
    50. Brush, SG
      Dynamics of theory change in chemistry: Part 2. Benzene and molecular orbitals, 1945-1980

      STUDIES IN HISTORY AND PHILOSOPHY OF SCIENCE
    51. Yamazaki, S; Taira, Z
      Coupling of alkynes promoted by Ru(CO)(3)(PPh3)(2) and carbon dioxide: syntheses and structures of (eta(4)-C4R2R2 ' CO) Ru(CO)(2)(PPh3) (R = R ' = Ph; R = Ph, R ' = C CPh) and {Ph2C4(C CPh)(2)}Ru(CO)(PPh3)(2)

      JOURNAL OF ORGANOMETALLIC CHEMISTRY
    52. Roidl, G; Enkelmann, V; Adams, RD; Bunz, UHF
      An alternative synthesis of Vollhardt's [1,2-diethynyl-3,4-bis(trimethylsilyl)cyclobutadiene]cyclopentadienylcobalt and selective formation of its dimer

      JOURNAL OF ORGANOMETALLIC CHEMISTRY
    53. Hartbaum, C; Fischer, H
      Synthesis of triynylcarbene complexes and of bi- and trinuclear complexes with heptatriynylidene C-7-bridges

      JOURNAL OF ORGANOMETALLIC CHEMISTRY
    54. Suresh, CH; Gadre, SR
      Clar's aromatic sextet theory revisited via molecular electrostatic potential topography

      JOURNAL OF ORGANIC CHEMISTRY
    55. Filatov, M; Shaik, S
      Application of spin-restricted open-shell Kohn-Sham method to atomic and molecular multiplet states

      JOURNAL OF CHEMICAL PHYSICS
    56. McNicholas, SJ; Manby, FR
      State-selective core-optimized spin-coupled theory

      INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
    57. Zilberg, S; Haas, Y
      The electron-pair origin of antiaromaticity: Spectroscopic manifestations

      INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
    58. Bridgeman, AJ; Rothery, J
      The bonding and structure of B-N sandwich complexes

      INORGANICA CHIMICA ACTA
    59. Chisholm, MH; Folting, K; Streib, WE; Wu, DD
      Dinuclear molybdenum and tungsten complexes with metal-metal triple bonds supported by p-tert-butylcalix[4]arene ligands

      INORGANIC CHEMISTRY
    60. Gerson, F; Huber, W; Merstetter, P; Persy, G; Soulen, RL; Spondlin, C; Wirz, J
      Powerful oxidizing properties of a planar [8]annulene: Tetrakis(perfluorocyclobuta)cyclooctatetraene and its radical anion

      HELVETICA CHIMICA ACTA
    61. Ichikawa, H; Yoshida, A; Kagawa, H; Aihara, J
      Interpretation of 'pi energy' and its linear additivity in polyenes

      BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
    62. Yoshizawa, K; Tachibana, M; Yamabe, T
      The B-1u and B-2u vibrational modes causing a D-6h to D-3h transition in benzene and in [18]- and [30]annulenes

      BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
    63. Randall, ML; Lo, PCK; Bonitatebus, PJ; Snapper, ML
      [2+2] photocycloaddition thermal retrocycloaddition. A new entry into functionalized 5-8-5 ring systems

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    64. HARTBAUM C; ROTH G; FISCHER H
      POLYNUCLEAR COMPLEXES WITH PROPYNYLIDENE C-3 BRIDGES - GENERAL SYNTHETIC ROUTE TO BIS(ETHYNYLCARBENE), TRIS(ETHYNYLCARBENE), AND TETRAKIS(ETHYNYLCARBENE) COMPLEXES

      EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
    65. BERTRAND G
      YLIDIC 4 PI-ELECTRON 4-MEMBERED LAMBDA(5)-PHOSPHORUS HETEROCYCLES - ELECTRONIC ISOMERS OF HETEROCYCLOBUTADIENES

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    66. GOGONEA V; SCHLEYER PV; SCHREINER PR
      CONSEQUENCES OF TRIPLET AROMATICITY IN 4N-PI-ELECTRON ANNULENES - CALCULATION OF MAGNETIC SHIELDINGS FOR OPEN-SHELL SPECIES

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    67. CHEN XY; LI CD; WU T; YAO TY; JU GZ
      STRUCTURE AND STABILITIES OF (HA1NH)(N) (N = 2-4)

      Theoretical chemistry accounts
    68. WANG H; BREZINSKY K
      COMPUTATIONAL STUDY ON THE THERMOCHEMISTRY OF CYCLOPENTADIENE DERIVATIVES AND KINETICS OF CYCLOPENTADIENONE THERMAL-DECOMPOSITION

      The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
    69. GONZALEZLAFONT A; VILLA J; LLUCH JM; BERTRAN J; STECKLER R; TRUHLAR DG
      VARIATIONAL TRANSITION-STATE THEORY AND TUNNELING CALCULATIONS WITH REORIENTATION OF THE GENERALIZED TRANSITION-STATES FOR METHYL CATION TRANSFER

      The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
    70. YU ZH; LI LT; FU W; LI LP
      CONFORMATIONS OF STILBENE-LIKE SPECIES AND NEW METHOD OF ENERGY PARTITION

      The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
    71. Zilberg, S; Haas, Y
      Two-state model of antiaromaticity: The triplet state. Is Hund's rule violated?

      JOURNAL OF PHYSICAL CHEMISTRY A
    72. Davies, AG; Ng, KM
      An EPR study of electron transfer reactions involving arenes and mercury(II) or thallium(III) salts

      JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
    73. YUN SH; YUN YS; PARK JK; SUN H
      THE POTENTIAL-ENERGY SURFACES AND DIPOLE-MOMENT FUNCTIONS OF NH2 BY AB-INITIO EFFECTIVE VALENCE SHELL HAMILTONIAN

      Bulletin of the Korean Chemical Society
    74. LEWARS E
      PYRAMIDANE - AN AB-INITIO STUDY OF THE C5H4 POTENTIAL-ENERGY SURFACE

      Journal of molecular structure. Theochem
    75. GERISCH M; KIRSCHBAUM K; BRUHN C; SCHMIDT H; DAVIES JA; STEINBORN D
      SYNTHESIS AND CHARACTERIZATION OF NOVEL DINUCLEAR AND CATIONIC CYCLOBUTADIENE PLATINUM COMPLEXES

      Journal of organometallic chemistry
    76. ANDRES JL; CASTANO O; MORREALE A; PALMEIRO R; GOMPERTS R
      POTENTIAL-ENERGY SURFACE OF CYCLOOCTATETRAENE

      The Journal of chemical physics
    77. Redington, RL
      State-specific vibrational anharmonicities in cyclobutadiene and evidence for fast automerization by (C4H4)-C-12

      JOURNAL OF CHEMICAL PHYSICS
    78. LARSSON S; RODRIGUEZMONGE L
      ROLE OF PI-STABILIZATION IN CYCLIC POLYENES

      International journal of quantum chemistry
    79. MITCHELL RH; CHEN YS; KHALIFA N; ZHOU PZ
      THE SYNTHESIS, AROMATICITY, AND NMR PROPERTIES OF [14]ANNULENE FUSED ORGANOMETALLICS - DETERMINATION OF THE EFFECTIVE BOND LOCALIZING ABILITY (RELATIVE AROMATICITY) AND DIAMAGNETIC ANISOTROPY OF SEVERAL ORGANOMETALLIC MOIETIES

      Journal of the American Chemical Society
    80. GLEITER R; MERGER M
      PHANES WITH 3-MEMBERED AND 4-MEMBERED RINGS AS BUILDING ELEMENTS

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    81. JEMMIS ED; SUBRAMANIAN G; KORKIN AA; HOFMANN M; SCHLEYER PV
      EXOTIC STRUCTURES OF SI2B2H4

      The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
    82. KOMAGUCHI K; SHIOTANI M
      ASYMMETRICALLY DISTORTED STRUCTURE, SELECTIVE BOND-LENGTH ALTERNATION, AND REACTIONS OF RADICAL CATIONS OF SILACYCLOHEXANES - AN ESR AND AB-INITIO MO STUDY

      The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory
    83. MIZOUCHI H; IKAWA A; FUKUTOME H
      ELECTRONIC-STRUCTURES OF IONS OF M-PHENYLENEBIS (PHENYLMETHYLENE)

      Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals
    84. BUNZ UHF
      A SOFT SPOT FOR ALKYNES

      Synlett
    85. BERSON JA
      HUCKEL,ERICH, PIONEER OF ORGANIC QUANTUM-CHEMISTRY - REFLECTIONS ON THEORY AND EXPERIMENT

      Angewandte Chemie, International Edition in English
    86. CAYTON RH; CHISHOLM MH; FOLTING K; WESEMANN JL; MOODLEY KG
      FURTHER-STUDIES OF THE REACTIVITY OF CYCLOPENTADIENYL, SUBSTITUTED CYCLOPENTADIENYL AND INDENYL LIGANDS WITH M2CL2(NME2)(4) (M=MO OR W) - CRYSTAL AND MOLECULAR-STRUCTURES OF MO-2(C9H7)(2)(NME2)(4) AND W-2(C5H4ME)(2)(NME2)(4)

      Journal of the Chemical Society. Dalton transactions
    87. HARRISON RM; BROTIN T; NOLL BC; MICHL J
      TOWARD A SQUARE-GRID POLYMER - SYNTHESIS AND STRUCTURE OF PEDESTAL-MOUNTED TETRAGONAL STAR CONNECTORS, C4R4-CO-C5Y5

      Organometallics
    88. METROPOULOS A; CHIU YN
      THE EFFECT OF CORRELATION ON THE JAHN-TELLER INSTABILITY OF CYCLOBUTADIENE

      Journal of molecular structure. Theochem
    89. GLUKHOVTSEV MN; BACH RD; LAITER S
      ISODESMIC AND HOMODESMOTIC STABILIZATION ENERGIES OF [N]ANNULENES ANDTHEIR RELEVANCE TO AROMATICITY AND ANTIAROMATICITY - IS ABSOLUTE ANTIAROMATICITY POSSIBLE

      Journal of molecular structure. Theochem
    90. SHAIK S; SHURKI A; DANOVICH D; HIBERTY PC
      A DIFFERENT STORY OF BENZENE

      Journal of molecular structure. Theochem
    91. KIYOBAYASHI T; YAMAMOTO K
      RESONANCE AND STRAIN ENERGIES IN NONPLANA R CYCLIC CONJUGATE MOLECULES - HOW THEY CONTROL THE THERMODYNAMIC STABILITY

      Yuki Gosei Kagaku Kyokaishi
    92. HROVAT DA; BORDEN WT
      AB-INITIO CALCULATIONS ON THE INTERCONVERSION OF HOMOCUB-1(9)-ENE ANDHOMOCUB-9-YLIDENE

      Molecular physics
    93. BOUHADIR G; BIEGER K; LIVOTTO P; REAU R; GORNITZKA H; DAHAN F; BERTRAND G
      THE VERSATILE BEHAVIOR OF A 1,2-LAMBDA(5)-AZAPHOSPHETE TOWARDS PROTICNUCLEOPHILES

      Journal of organometallic chemistry
    94. MOORE L; LUBINSKI R; BASCHKY MC; DAHLKE GD; HARE M; ARROWOOD T; GLASOVAC Z; ECKERTMAKSIC M; KASS SR
      BENZOCYCLOPROPENYL ANION - A STABLE 8-PI-ELECTRON SPECIES

      Journal of organic chemistry
    95. WIBERG KB
      PROPERTIES OF SOME CONDENSED AROMATIC SYSTEMS

      Journal of organic chemistry
    96. KILIC H; BALCI M; YURTSEVER E
      A NEW ANTIAROMATIC COMPOUND - 1,4-BIPHENYLENEQUINONE SYNTHESIS AND TRAPPING REACTIONS

      Journal of organic chemistry
    97. GLUKHOVTSEV M
      AROMATICITY TODAY - ENERGETIC AND STRUCTURAL CRITERIA

      Journal of chemical education
    98. PANIAGUA JC; MOYANO A
      LOCALIZATION-CONSISTENT ELECTRONIC-ENERGY PARTITIONS

      International journal of quantum chemistry
    99. BELANZONI P; FANTACCI S; RE N; ROSI M; SGAMELLOTTI A; FLORIANI C
      OLIGOMERIZATION OF THE PH3CUC=CCUPH3 ACETYLIDE TOWARD THE FORMATION OF (PH3CUC)(N) (N=4, 6, 8) METAL CARBIDES - A THEORETICAL-STUDY BASED ON DENSITY-FUNCTIONAL THEORY

      Inorganic chemistry
    100. GIMARC BM; ZHAO M
      STRAIN AND RESONANCE ENERGIES IN MAIN-GROUP HOMOATOMIC RINGS AND CLUSTERS

      Coordination chemistry reviews


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Documento generato il 22/01/21 alle ore 05:29:26