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    1. Barrero, AF; Alvarez-Manzaneda, EJ; Alvarez-Manzaneda, R; Chahboun, R; Meneses, R; Cuerva, JM; Aparicio, M; Romera, JL
      Approach to the synthesis of antitumor quassinoids from labdane diterpenes: An efficient synthesis of a picrasane-related intermediate

      ORGANIC LETTERS
    2. Grossman, RB; Rasne, RM
      Short total syntheses of both the putative and actual structures of the clerodane diterpenoid (+/-)-sacacarin by double annulation

      ORGANIC LETTERS
    3. Cahard, D; Duhamel, P
      Alkoxide-mediated preparation of enolates from silyl enol ethers and enol acetates - From discovery to synthetic applications

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    4. Bruggemann, M; Holst, C; Hoppe, D
      First enantioselective total synthesis of both (+)- and (-)-metachromin A

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    5. Xing, XC; Demuth, M
      Application of photoinduced biomimetic cascade cyclizations of terpenoid polyalkenes for the synthesis of (+/-)-stypoldione

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    6. Kurosawa, S; Bando, M; Mori, K
      Synthesis of (1R,4R,5S)-(+)-acoradiene, the structure proposed for the aggregation pheromone of the broad-horned flour beetle

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    7. Costantino, V; Fattorusso, E; Imperatore, C; Mangoni, A
      Plaxyloside from the marine sponge Plakortis simplex: an improved strategyfor NMR structural studies of carbohydrate chains

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    8. Bianco, A; Celona, D; Di Rita, S; Guiso, M; Melchioni, C; Umani, F
      Chiral synthons from the iridoid glucoside antirrhinoside - Synthesis of acarbocyclic homonucleoside analogue

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    9. Schuhr, CA; Hecht, S; Kis, K; Eisenreich, W; Wungsintaweekul, J; Bacher, A; Rohdich, F
      Studies on the non-mevalonate pathway - Preparation and properties of isotope-labeled 2C-methyl-D-erythritol 2,4-cyclodiphosphate

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    10. Okochi, T; Mori, K
      New enantioselective synthesis of (10R,11S)-(+)-juvenile hormones I and II

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    11. Schrader, W; Geiger, J; Godejohann, M; Warscheid, B; Hoffmann, T
      An analytical approach for a comprehensive study of organic aerosols

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    12. Nevalainen, M; Koskinen, AMP
      Synthesis of a 10-membered carbocycle by olefin metathesis

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    13. Zabaras, D; Wyllie, SG
      The effect of mechanical wounding on the composition of essential oil fromOcimum minimum L. leaves

      MOLECULES
    14. Hou, AJ; Yang, H; Liu, YZ; Zhao, QS; Lin, ZW; Sun, HD
      Novel ent-kaurane diterpenoids from Isodon xerophilus

      CHINESE JOURNAL OF CHEMISTRY
    15. Roshchina, VV
      Molecular-cellular mechanisms in pollen allelopathy

      ALLELOPATHY JOURNAL
    16. Iwamoto, M; Ohtsu, H; Tokuda, H; Nishino, H; Matsunaga, S; Tanaka, R
      Anti-tumor promoting diterpenes from the stem bark of Thuja standishii (Cupressaceae)

      BIOORGANIC & MEDICINAL CHEMISTRY
    17. Gabriels, S; Van Haver, D; Vandewalle, M; De Clercq, P; Verstuyf, A; Bouillon, R
      Development of analogues of 1 alpha,25-dihydroxyvitamin D-3 with biased side chain orientation: Methylated des-C,D-homo analogues

      CHEMISTRY-A EUROPEAN JOURNAL
    18. Cespedes, CL; Alarcon, J; Aranda, E; Becerra, J; Silva, M
      Insect growth regulator and insecticidal activity of beta-dihydroagarofurans from Maytenus spp. (Celastraceae)

      ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES
    19. Cespedes, CL; Martinez-Vazquez, M; Calderon, JS; Salazar, JR; Aranda, E
      Insect growth regulatory activity of some extracts and compounds from Parthenium argentatum on fall armyworm Spodoptera frugiperda

      ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES
    20. Gavagnin, M; Mollo, E; Calado, G; Fahey, S; Ghiselin, M; Ortea, J; Cimino, G
      Chemical studies of porostome nudibranchs: comparative and ecological aspects

      CHEMOECOLOGY
    21. Abad, A; Agullo, C; Cunat, AC; Navarro, I; de Arellano, MCR
      A simple synthetic approach to trachylobane, beyerane, and atisane diterpenoids from carvone

      SYNLETT
    22. Basabe, P; Estrella, A; Marcos, IS; Diez, D; Lithgow, AM; White, AJP; Williams, DJ; Urones, JG
      Prehispanolone analogs: Stereochemistry control at C-5 in the preparation of 1-oxaspiro[4,5]decane fused systems and related compounds

      SYNLETT
    23. O'Connor, SJ; Overman, LE; Rucker, PV
      Use of sequential intramolecular Heck cyclizations for preparing bicyclo[3.2.1]octane fragments of tetracyclic stemodane and stemarane diterpenes

      SYNLETT
    24. Namba, AM; Leon, S; da Silva, GVJ; Aleman, C
      Force-field parametrization and molecular dynamics simulations of p-menthan-3,9-diols: a family of amphiphilic compounds derived from terpenoids

      JOURNAL OF COMPUTER-AIDED MOLECULAR DESIGN
    25. Brun, G; Bessiere, JM; Dijoux-Franca, MG; David, B; Mariotte, AM
      Volatile components of Catharanthus roseus (L.) G. Don (Apocynaceae)

      FLAVOUR AND FRAGRANCE JOURNAL
    26. Kalemba, D; Marschall, H; Bradesi, P
      Constituents of the essential oil of Solidago gigantea Ait. (giant goldenrod)

      FLAVOUR AND FRAGRANCE JOURNAL
    27. Piovano, M; Chamy, MC; Garbarino, JA
      Studies on Chilean lichens XXXI. Additions to the chemistry of Pseudocyphellaria.

      BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA
    28. Ping, LY; Shen, YB; Jin, YJ
      Volatiles released in succession from artificially damaged ashleaf maple leaves

      AUSTRALIAN JOURNAL OF PLANT PHYSIOLOGY
    29. Sangwan, NS; Farooqi, AHA; Shabih, F; Sangwan, RS
      Regulation of essential oil production in plants

      PLANT GROWTH REGULATION
    30. Capon, RJ; Jenkins, A; Rooney, F; Ghisalberti, EL
      Structure revision and assignment of absolute stereochemistry of a marine C-21 bisfuranoterpene

      JOURNAL OF NATURAL PRODUCTS
    31. Furbacher, TR; Gunatilaka, AAL
      Catalytic inhibition of topoisomerase II alpha by demethylzeylasterone, a 6-oxophenolic triterpenoid from Kokoona zeylanica

      JOURNAL OF NATURAL PRODUCTS
    32. Yoshida, K; Furihata, K; Yamane, H; Omori, T
      Metabolism of 18 beta-glycyrrhetinic acid in Sphingomonas paucimobilis strain G5

      BIOTECHNOLOGY LETTERS
    33. Williams, L; Evans, PE; Bowers, WS
      Defensive chemistry of an aposematic bug, Pachycoris stallii uhler and volatile compounds of its host plant Croton californicus Muell.-Arg.

      JOURNAL OF CHEMICAL ECOLOGY
    34. Van Poecke, RMP; Posthumus, MA; Dicke, M
      Herbivore-induced volatile production by Arabidopsis thaliana leads to attraction of the parasitoid Cotesia rubecula: Chemical, behavioral, and gene-expression analysis

      JOURNAL OF CHEMICAL ECOLOGY
    35. Harrowven, DC; Wilden, JD; Tyte, MJ; Hursthouse, MB; Coles, SJ
      A new approach to the pseudopterosins using an arene alkylation with a gamma-methylene-gamma-butyrolactone

      TETRAHEDRON LETTERS
    36. Harrowven, DC; Tyte, MJ
      Towards colombiasin A

      TETRAHEDRON LETTERS
    37. Ovenden, SPB; Yew, ALS; Glover, RP; Ng, S; Rossant, CJ; Regalado, JC; Soejarto, DD; Buss, AD; Butler, MS
      Actephilol A and epiactephilol A: two novel aromatic terpenoids isolated from Actephila excelsa

      TETRAHEDRON LETTERS
    38. Kenmoku, H; Kato, N; Shimada, M; Omoto, M; Mori, A; Mitsuhashi, W; Sassa, T
      Isolation of (-)-cyatha-3,12-diene, a common biosynthetic intermediate of cyathane diterpenoids, from an erinacine-producing basidiomycete, Hericium erinaceum, and its formation in a cell-free system

      TETRAHEDRON LETTERS
    39. Lagnel, BMF; de Groot, A; Morin, C
      Synthesis of B-ring functionalised intermediates for the preparation of 1,9-dideoxy-forskolin derivatives

      TETRAHEDRON LETTERS
    40. Uyehara, T; Onda, K; Nozaki, N; Karikomi, M; Ueno, M; Sato, T
      The first total synthesis of (+/-)-2-thiocyanatoneo pupukeanane based on apinacol-type rearrangement

      TETRAHEDRON LETTERS
    41. Morimoto, Y; Iwai, T; Kinoshita, T
      Total synthesis and determination of the absolute configuration of (-)-longilene peroxide

      TETRAHEDRON LETTERS
    42. Takao, K; Hara, M; Tsujita, T; Yoshida, K; Tadano, K
      Total synthesis of (+)-cheimonophyllon E, a bisabolane sesquiterpenoid

      TETRAHEDRON LETTERS
    43. Matsuura, T; Terada, Y; Yamamura, S
      Efforts towards the synthesis of jatrapholane diterpenes: a biomimetic transannular reaction approach

      TETRAHEDRON LETTERS
    44. Hoeffler, JF; Grosdemange-Billiard, C; Rohmer, M
      Elucidation of the 2-C-methyl-D-erythritol 4-phosphate pathway for isoprenoid biosynthesis: straightforward syntheses of enantiopure 1-deoxy-D-xylulose from pentose derivatives

      TETRAHEDRON LETTERS
    45. Mehta, G; Srinivas, K
      Enantioselective total syntheses of the novel tricyclic sesquiterpene hydrocarbons (+)- and (-)-kelsoene. Absolute configuration of the natural product

      TETRAHEDRON LETTERS
    46. Harrowven, DC; Lucas, MC; Howes, PD
      The first total synthesis of (+/-)-1-desoxyhypnophilin

      TETRAHEDRON
    47. Gavagnin, M; Mollo, E; Castelluccio, F; Ghiselin, MT; Calado, G; Cimino, G
      Can molluscs biosynthesize typical sponge metabolites? The case of the nudibranch Doriopsilla areolata

      TETRAHEDRON
    48. Zambrini, L; Fabris, F; De Lucchi, O; Gardenal, G; Visentin, F; Canovese, L
      Heck self-condensation of polycyclic haloalkenes: the case of (1R)-2-iodobornene

      TETRAHEDRON
    49. Matsuda, H; Morikawa, T; Ninomiya, K; Yoshikawa, M
      Absolute stereostructure of carabrane-type sesquiterpene and vasorelaxant-active sesquiterpenes from Zedoariae Rhizoma

      TETRAHEDRON
    50. Fraga, BM; Hernandez, MG; Gonzalez, P; Lopez, M; Suarez, S
      Biotransformation of the diterpene ribenone by Mucor plumbeus

      TETRAHEDRON
    51. Harrowven, DC; Lucas, MC; Howes, PD
      The synthesis of a natural product family: from debromoisolaurinterol to the aplysins

      TETRAHEDRON
    52. Yick, CY; Wong, HNC
      Regiospecific substitution of the carbon-boron bond of tris(4-methylfuran-3-yl)boroxine: a model ring C -> BC -> ABC approach towards eudesmanolides

      TETRAHEDRON
    53. Lee, HJ; Ravn, MM; Coates, RM
      Synthesis and characterization of abietadiene, levopimaradiene, palustradiene, and neoabietadiene: hydrocarbon precursors of the abietane diterpene resin acids

      TETRAHEDRON
    54. Costantino, V; Fattorusso, E; Imperatore, C; Mangoni, A
      A biosynthetically significant new bacteriohopanoid present in large amounts in the Caribbean sponge Plakortis simplex

      TETRAHEDRON
    55. Ortega, A; Garcia, PE; Cardenas, J; Mancera, C; Marquina, S; Garduno, MLD; Maldonado, E
      Methyl dodonates, a new type of diterpenes with a modified clerodane skeleton from Dodonaea viscosa

      TETRAHEDRON
    56. Manriquez, CP; Souto, ML; Gavin, JA; Norte, M; Fernandez, JJ
      Several new squalene-derived triterpenes from Laurencia

      TETRAHEDRON
    57. Samajdar, S; Ghatak, A; Banerjee, S; Ghosh, S
      High diastereoselectivity in Claisen rearrangement in a sterically congested cyclopentane system. Total synthesis of (+/-)-beta-necrodol

      TETRAHEDRON
    58. Sun, HD; Qiu, SX; Lobkovsky, EB; Lin, LZ; Farnsworth, NR; Clardy, J; Fong, HHS
      Crystal and molecular structures of a natural equimolecular mixture of twoepimeric diterpenes

      TETRAHEDRON
    59. Hohmann, J; Evanics, F; Dombi, G; Szabo, P
      Euphosalicin, a new diterpene polyester with multidrug resistance reversing activity from Euphorbia salicifolia

      TETRAHEDRON
    60. Cramarossa, MR; Forti, L; Pagnoni, UM; Vidali, M
      Cyclization of citronellal to menthone and isomenthone catalyzed by Al/Fe-Pillared Clays

      SYNTHESIS-STUTTGART
    61. Cantrell, CL; Franzblau, SG; Fischer, NH
      Antimycobacterial plant terpenoids

      PLANTA MEDICA
    62. Nagashima, F; Asakawa, Y
      Sesqui- and diterpenoids from two Japanese and three European liverworts

      PHYTOCHEMISTRY
    63. Asakawa, Y
      Recent advances in phytochemistry of bryophytes-acetogenins, terpenoids and bis(bibenzyl)s from selected Japanese, Taiwanese, New Zealand, Argentinean and European liverworts

      PHYTOCHEMISTRY
    64. Tanaka, R; Mori, H; Yamamoto, M; Katsumura, S
      Significant acceleration of 6 pi-azaelectrocyclization resulting from a remarkable substituent effect and formal synthesis of the ocular age pigment A2-E by a new method for substituted pyridine synthesis

      JOURNAL OF ORGANIC CHEMISTRY
    65. Jauch, J
      A new protocol for Baylis-Hillman reactions: Chirality transfer in a lithium phenylselenide induced Tandem-Michael-Aldol - Retro-Michael reaction

      JOURNAL OF ORGANIC CHEMISTRY
    66. Fontana, A; Kelly, MT; Prasad, JD; Andersen, RJ
      Evidence for the biosynthesis of squalene via the methylerythritol phosphate pathway in a Streptomyces sp obtained from a marine sediment

      JOURNAL OF ORGANIC CHEMISTRY
    67. Hecht, S; Kis, F; Eisenreich, W; Amslinger, S; Wungsintaweekul, J; Herz, S; Rohdich, F; Bacher, A
      Enzyme-assisted preparation of isotope-labeled 1-deoxy-D-xylulose 5-phosphate

      JOURNAL OF ORGANIC CHEMISTRY
    68. Tripathi, AK; Prajapati, V; Aggarwal, KK; Kumar, S
      Toxicity, feeding deterrence, and effect of activity of 1,8-cineole from Artemisia annua on progeny production of Tribolium castanaeum (Coleoptera : Tenebrionidae)

      JOURNAL OF ECONOMIC ENTOMOLOGY
    69. Dai, JM; Yaylayan, VA; Raghavan, GSV; Pare, JR; Liu, Z
      Multivariate calibration for the determination of total azadirachtin-related limonoids and simple terpenoids in neem extracts using vanillin assay

      JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
    70. Ashitani, T; Ujike, M; Nagahama, S; Ueno, T; Sakai, K
      Characterization of sugi (Cryptomeria japonica) bark extracts

      MOKUZAI GAKKAISHI
    71. Brennan, EB; Weinbaum, SA
      Stylet penetration and survival of three psyllid species on adult leaves and 'waxy' and 'de-waxed' juvenile leaves of Eucalyptus globulus

      ENTOMOLOGIA EXPERIMENTALIS ET APPLICATA
    72. Malkov, AV; Kocovsky, P
      Tetrahydrocannabinol revisited: Synthetic approaches utilizing molybdenum catalysts

      COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
    73. Martin, P; Archier, P; Vieillescazes, C; Pistre, MS
      HPLC coupled with fluorimetric detection for the identification of naturalresins in archaeological materials

      CHROMATOGRAPHIA
    74. Cheng, MJ; Tsai, IL; Chen, IS
      Chemical constituents from Strychnos cathayensis

      JOURNAL OF THE CHINESE CHEMICAL SOCIETY
    75. Sun, DA; Sauriol, F; Mamer, O; Zamir, LO
      Reanalysis of the biotransformation of 4(20),11(12)-taxadiene derivatives

      CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
    76. Penuelas, J; Llusia, J
      The complexity of factors driving volatile organic compound emissions by plants

      BIOLOGIA PLANTARUM
    77. Grassmann, J; Schneider, D; Weiser, D; Elstner, EE
      Antioxidative effects of lemon oil and its components on copper induced oxidation of low density lipoprotein

      ARZNEIMITTEL-FORSCHUNG-DRUG RESEARCH
    78. Zini, CA; Augusto, F; Christensen, E; Smith, BP; Caramao, EB; Pawliszyn, J
      Monitoring biogenic volatile compounds emitted by Eucalyptus citriodora using SPME

      ANALYTICAL CHEMISTRY
    79. Ferreira, MJP; Brant, AJC; Rodrigues, GV; Emerenciano, VP
      Automatic identification of terpenoid skeletons through C-13 nuclear magnetic resonance data disfunctionalization

      ANALYTICA CHIMICA ACTA
    80. Okauchi, T; Teshima, T; Hayashi, K; Suetsugu, N; Minami, T
      Regioselective proton abstraction and 1,3-migration of a phosphorus group in 1,3-dienes by iron coordination: A new method for the synthesis of alpha-phosphono-alpha,beta-unsaturated ketones

      JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
    81. Lockwood, GB
      Techniques for gas chromatography of volatile terpenoids from a range of matrices

      JOURNAL OF CHROMATOGRAPHY A
    82. Chan, KK
      Quantitation of monoterpenoid compounds with potential medicinal use in biological fluids

      JOURNAL OF CHROMATOGRAPHY A
    83. Cserhati, T; Forgacs, E
      Liquid chromatographic separation of terpenoid pigments in foods and food products

      JOURNAL OF CHROMATOGRAPHY A
    84. Li, HB; Chen, F
      Preparative isolation and purification of six diterpenoids from the Chinese medicinal plant Salvia miltiorrhiza by high-speed counter-current chromatography

      JOURNAL OF CHROMATOGRAPHY A
    85. Yang, FQ; Ito, Y
      pH-zone-refining counter-current chromatography of lappaconitine from Aconitum sinomontanum Nakai I. Separation of prepurified extract

      JOURNAL OF CHROMATOGRAPHY A
    86. Geiger, J; Korte, EH; Schrader, W
      Development of a simple gradient LC-IR interface for the detection of terpenoids from the alpha-pinene-ozone reaction

      JOURNAL OF CHROMATOGRAPHY A
    87. Lacey, ME; Tan, ZJ; Webb, AG; Sweedler, JV
      Union of capillary high-performance liquid chromatography and microcoil nuclear magnetic resonance spectroscopy applied to the separation and identification of terpenoids

      JOURNAL OF CHROMATOGRAPHY A
    88. Talbot, HM; Watson, DF; Murrell, JC; Carter, JF; Farrimond, P
      Analysis of intact bacteriohopanepolyols from methanotrophic bacteria by reversed-phase high-performance liquid chromatography-atmospheric pressure chemical ionisation mass spectrometry

      JOURNAL OF CHROMATOGRAPHY A
    89. Srikrishna, A; Vijaykumar, D
      An enantiospecific approach to pinguisanes from (R)-carvone. Total synthesis of (+)-pinguisenol

      JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
    90. Hersel, U; Steck, M; Seifert, K
      A new route to 2,7-and 7-functionalized labdanes

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    91. Kurosawa, S; Mori, K
      Pheromone synthesis, CC - Synthesis of (S)-9-methylgermacrene-B, the male-produced sex pheromone of the sandfly Lutzomyia longipalpis from Lapinha, Brazil, and its (R)-isomer

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    92. Yajima, A; Mori, K
      Diterpenoid total synthesis, XXXII Synthesis and absolute configuration of(-)-phytocassane D, a diterpene phytoalexin isolated from the rice plant, Oryza sativa

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    93. Domon, K; Mori, K
      Pheromone synthesis, CCV - Short synthesis of vesperal [(S)-10-oxoisopiperitenone], the female sex pheromone of the longhorn beetle (Vesperus xatarti), and of its enantiomer

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    94. Tsujimori, H; Bando, M; Mori, K
      Synthetic microbial chemistry XXXII - Synthesis and absolute configurationof hongoquercin A, an antibacterial sesquiterpene-substituted orsellinic acid isolated as a fungal metabolite

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    95. Blay, G; Cardona, L; Garcia, B; Lahoz, L; Pedro, JR
      Synthesis of elemane bis-lactones from santonin - Synthesis of the reported structure of seco-isoerivanin pseudo acid and formal synthesis of (+)-8-deoxyvernolepin

      EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
    96. Kraft, P; Bajgrowicz, JA; Denis, C; Frater, G
      Odds and trends: Recent developments in the chemistry of odorants

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    97. Zhou, SZ; Sey, M; De Clercq, PJ; Milanesio, M; Viterbo, D
      A model for the nonenzymatic BCD cyclization of squalene

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    98. Beifuss, U; Tietze, M; Baumer, S; Deppenmeier, U
      Methanophenazine: Structure, total synthesis, and function of a new cofactor from methanogenic archaea

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    99. Hioki, H; Kanehara, C; Ohnishi, Y; Umemori, Y; Sakai, H; Yoshio, S; Matsushita, M; Kodama, M
      What is the structure of glabrescol? Stereoselective synthesis of reportedglabrescol

      ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
    100. Fakhri, SA; Yousefi, BH
      Synthesis and characterization of 8-hydroxy-5,8,9,10-tetrahydro-6H-benzocycloocten-7-one, 5,6,9,10-tetrahydrobenzocyclo-octene-7,8-dione and 6,7,10,11-tetrahydrobenzocycloocta-[b]quinoxaline

      ACTA CHIMICA SLOVENICA


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Documento generato il 05/08/20 alle ore 04:35:33