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Molybdenum-catalyzed asymmetric allylic alkylation reactions using Mo(CO)(6) as precatalyst
ADVANCED SYNTHESIS & CATALYSIS
Chiral phosphine-free Pd-mediated asymmetric allylation of prochiral enolate with a chiral phase-transfer catalyst
ORGANIC LETTERS
Synthesis and application of chiral P,N-ligands with pseudo-meso and pseudo-C-2 symmetry
ORGANIC LETTERS
Utilization of industrial waste materials. Part 20. Stereoselective cycloaddition of silylenes and a disilene to an enantiomerically pure cyclic ketimine derived from an industrial waste material
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
On the evidence for formation of an exo-pi-allyl complex intermediate in the Pd-0-catalyzed alkylation of a bicyclic allylic diacetate
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Experimental evidence on the existence of an exo-pi-allyl complex intermediate in the Pd-0-catalyzed alkylation of a bicyclic allylic diacetate with stabilized nucleophiles
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Chelated enolates of amino acid esters - New and efficient nucleophiles for isomerization-free, stereoselective palladium-catalyzed allylic substitutions
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Palladium(0)-catalyzed isomerization of (Z)-1,4-diacetoxy-2-butene - Dependence of eta(1)- or eta(3)-allylpalladium as a key intermediate on the solvent polarity
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
A versatile and high-yield route to active and well-defined catalysts [Ru(bisphosphane)(H)(solvent)(3)](BF4)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Testing racemic chiral catalysts for kinetic resolution potential
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Transition metal catalysis using functionalized dendrimers
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Reversal of stereochemistry in enantioselective transformations. Can they be planned or are they just accidental?
CURRENT ORGANIC CHEMISTRY
Preparation and application of polymer-supported pi-allylpalladium complexas a chiral catalyst in the asymmetric allylic alkylation
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Synthesis of planar chiral tricarbonylcyclopentadienylmanganese complexes using a Mn(CO)(3)(+) transfer reaction
CHEMICAL COMMUNICATIONS
Microwave-assisted high-speed chemistry: a new technique in drug discovery
DRUG DISCOVERY TODAY
Highly distorted d(8)-rhodium(+I) and d(10)-rhodium(-I) complexes: synthesis, reactivity, and structures in solution and solid state
NEW JOURNAL OF CHEMISTRY
1,1 '-binaphthylazepine-based ligands for asymmetric catalysis. Part 1: Preparation and characterization of some new aminoalcohols and diamines
TETRAHEDRON-ASYMMETRY
1,1 '-binaphthyiazepine-based ligands for asymmetric catalysis. Part 2: New aminoalcohols as chiral ligands in the enantioselective addition of ZnEt2to aromatic aldehydes
TETRAHEDRON-ASYMMETRY
Synthesis of novel N,O-planar chiral [2,2]paracyclophane ligands and theirapplication as catalysts in the addition of diethylzinc to aldehydes
TETRAHEDRON-ASYMMETRY
Determination of absolute configuration of (pi-allyl)palladium complexes by NMR spectroscopy and stereoselective complexation
CHEMISTRY-A EUROPEAN JOURNAL
Solid-phase organometallic synthesis
CHEMISTRY-A EUROPEAN JOURNAL
Isotopic desymmetrisation as a stereochemical probe
SYNLETT
2-(phosphinoaryl)pyridine ligand (2): Asymmetric allylic alkylation of 2-cycloalkenyl carboxylate
SYNLETT
C-2-symmetric bissulfoximines in palladium-catalyzed allylic alkylations
SYNLETT
A concise synthesis of (-)-methylenolactocin and (-)- phaseolinic acid from (6S,9S)-tetradec-7-yne-6,9-diol
SYNLETT
On the source of transfer of stereochemical information in ligands for Pd-catalyzed AAA reactions
SYNLETT
P-chirogenic monodentate phosphine ligands bearing 2-biphenyl group
SYNLETT
Multifactorial analysis in the study of hydroformylation of oct-1-ene using supported aqueous phase catalysis
CATALYSIS TODAY
Recent advances in homogeneous catalysis using platinum complexes
POLYHEDRON
Mechanism of the eta(3)-eta(1)-eta(3) isomerization in allylpalladium complexes: Solvent coordination, ligand, and substituent effects
ORGANOMETALLICS
Synthesis of beta-cyclodextrin-functionalized (2S,4S)-(-)-4-(diphenylphosphino)-2-(diphenylphosphinomethyl) ligands and their rhodium and platinum complexes
ORGANOMETALLICS
Participation of (eta(3)-allyl)ruthenium(II) complexes in C-C bond formation and C-C bond cleavage. A theoretical study
ORGANOMETALLICS
Cationic palladium catalyzed enyne cycloreductions
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Regioselective rhodium-catalyzed allylic alkylation/ring-closing metathesis approach to carbocycles
TETRAHEDRON LETTERS
First enantioselective total synthesis of both enantiomers of lancifolol. Correlation: Absolute configuration/specific rotation
TETRAHEDRON LETTERS
Chiral tricarbonyl(eta(6)arene)chromium complexed diphosphanes. Highly enantioselective rhodium-mediated hydrogenation of ketones
TETRAHEDRON LETTERS
Rhodium-catalysed asymmetric ring opening reactions with carboxylate nucleophiles
TETRAHEDRON
Axially chiral bidentate ligands in asymmetric catalysis
TETRAHEDRON
Synthetic organic chemistry based on N-Ar axis
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN
Chiral ferrocenylthiazolidines, new ligands for palladium complexes
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Synthesis, bonding and dynamic behavior of fac-[Mo(II)(CO)(2)(eta(3)-allyl)] derivatives
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Transition metal complexes with the C-1-symmetric diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to enantioselective catalysis in different phase systems
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Highly enantioselective rh-catalyzed hydrogenation based on phosphine-phosphite ligands derived from carbohydrates
JOURNAL OF ORGANIC CHEMISTRY
First examples of enantioselective palladium-catalyzed thiocarbonylation of prochiral 1,3-conjugated dienes with thiols and carbon monoxide: Efficient synthesis of optically active beta,gamma-unsaturated thiol esters
JOURNAL OF ORGANIC CHEMISTRY
Phosphite derivatives of (2R)-2-pyrrolidin-1-yl-butan-1-ol: synthesis, chelation with rhodium(I) and testing in the palladium-catalysed allylic alkylation
INORGANICA CHIMICA ACTA
Rearrangements in allylpalladium complexes with hemilabile chelating ligands
HELVETICA CHIMICA ACTA
1,6-asymmetric induction during the conjugate addition of arylcopper reagents to a chiral sulfinyl-substituted pyrrolyl alpha,beta-unsaturated amide
CHEMICAL & PHARMACEUTICAL BULLETIN
Transition metals and carbohydrates: the methyl-4,6-O-benzylidene-2,3-diazo-2,3-dideoxy-alpha-D-mannopyranoside skeleton as building block for new chiral nitrogen chelates
CARBOHYDRATE RESEARCH
BINAPS - An axially chiral P,S-heterodonor ligand for asymmetric catalysisbased on binaphthalene backbone
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Novel use of ring strain to control regioselectivity: Alkene-directed, palladium-catalyzed allylation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
A catalytic asymmetric Wagner-Meerwein shift
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Effects of halide ligands and protic additives on enantioselectivity and reactivity in rhodium-catalyzed asymmetric ring-opening reactions
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Geminal dicarboxylates as carbonyl surrogates for asymmetric synthesis. Part I. Asymmetric addition of malonate nucleophiles
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Wide bite angle diphosphines: Xantphos ligands in transition metal complexes and catalysis
ACCOUNTS OF CHEMICAL RESEARCH
Ligand tuning in asymmetric catalysis: Mono- and bis-phospholanes for a prototypical Pd-catalyzed asymmetric allylation reaction
ORGANIC LETTERS
New potential (P,S)-ligands containing tetrathiafulvalene
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
Phosphine-phosphite, a new class of auxiliaries in highly active and enantioselective hydrogenation
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Chiral 4-(diphenylphosphanyl)-1-(dialkylamino)butane ligands - Synthesis, applications in asymmetric alkylation and theoretical study
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Evidence of formation of an exo-pi-allyl complex intermediate in the Pd-0-catalyzed alkylation of a bicyclic allylic diacetate with stabilized carbonnucleophiles
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Enantioselective preparation of 2,4-disubstituted azetidines
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Asymmetric synthesis of alpha-methyl alpha-amino acids through diastereoselective alkylation under mild reaction conditions of an iminic alanine template with a 1,2,3,6-tetrahydro-2-pyrazinone structure
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Axially chiral phosphinamine ligands in asymmetric catalysis
CURRENT ORGANIC CHEMISTRY
Asymmetric catalysis: A ligand's eye view
CURRENT ORGANIC CHEMISTRY
Phosphine-phosphite, a new class of auxiliaries in highly active and enantioselective hydrogenation
CHEMICAL COMMUNICATIONS
Synthesis of novel diphosphines from D-(+)-glucose. Use in asymmetric hydrogenation
TETRAHEDRON-ASYMMETRY
Synthesis of a new class of chiral aminoalcohols and their application in the enantioselective addition of diethylzinc to aldehydes
TETRAHEDRON-ASYMMETRY
Preparation of chiral C-2-symmetrical 1,1 '-disubstituted ferrocenes
TETRAHEDRON-ASYMMETRY
A modular approach to structurally diverse bidentate chelate ligands for transition metal catalysis
CHEMISTRY-A EUROPEAN JOURNAL
Palladium-catalyzed allylic alkylation using a novel chiral imino-phosphine ligand derived from 1-mesitylethylamine
SYNLETT
A new quinazoline-containing axially chiral ligand for asymmetric catalysis
POLYHEDRON
Electronically and sterically induced structural distortions in square-planar d(8) complexes
ORGANOMETALLICS
Regioselectivity of the nucleophilic addition to (eta(3)-allyl) palladium complexes. A theoretical study
ORGANOMETALLICS
Iridium-catalyzed crossed aldol coupling and a new concept to form an Ir-Si species
TETRAHEDRON LETTERS
Enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using new chiral P,N ligands composed of (S)-2-alkyl-2-aminoethylphosphines and alpha-substituted pyridines
TETRAHEDRON LETTERS
Remarkable rate enhancement of palladium-catalyzed allylic alkylation in water using a colloidal dispersion system
TETRAHEDRON LETTERS
Role of the planar chirality of imine-phosphine hybrid ligands bearing chromium tricarbonyl in the palladium-catalyzed asymmetric allylic alkylation
TETRAHEDRON LETTERS
Synthesis and resolution of 2-methyl-Quinazolinap, a new atropisomeric phosphinamine ligand for asymmetric catalysis
TETRAHEDRON LETTERS
Enantioselective cyclopropanation of styrene catalysed by copper(I) complexes with chiral oxazolines
TETRAHEDRON
Application of the molybdenum-catalysed hydrostannation towards a flexiblesynthesis of substituted unsaturated amino acids
SYNTHESIS-STUTTGART
Microwave-mediated palladium-catalyzed asymmetric allylic alkylation; an example of highly selective fast chemistry
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Lanthanide-catalyzed asymmetric 1,3-dipolar cycloaddition of nitrones to alkenes using 3,3 '-bis(2-oxazolyl)-1,1 '-bi-2-naphthol (BINOL-Box) ligands
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Recent progress in asymmetric heterogeneous catalysis: use of polymer-supported catalysts
JOURNAL OF ORGANOMETALLIC CHEMISTRY
pi-Allyliridium(I) complexes, Ir(eta(3)-CH2CHCHAr)(CO)(PPh3)(2) (Ar = Ph, C6H4Me-p, C6H4Br-p). Comparison of their structures and chemical propertieswith analogous Rh complexes
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Stereodivergent synthesis of (E)- and (Z)-2-Alken-4-yn-1-ols from 2-propynoic acid: A practical route via 2-alke-4-ynoates
JOURNAL OF ORGANIC CHEMISTRY
An efficient, general asymmetric synthesis of carbocyclic nucleosides: Application of an asymmetric aldol/ring-closing metathesis strategy
JOURNAL OF ORGANIC CHEMISTRY
Room temperature ring-opening cyclization reactions of 2-vinylaziridines with isocyanates, carbodiimides, and isothiocyanates catalyzed by [Pd(OAc)(2)]/PPh3
JOURNAL OF ORGANIC CHEMISTRY
Stereochemistry of formation of the beta-ring of lycopene: Biosynthesis of(1R,1 ' R)-beta,beta-[16,16,16,16 ',16 ',16 '-H-2(6)]carotene from [16,16,16,16 ',16 ',16 '-H-2(6)]lycopene in Flavobacterium R 1560
HELVETICA CHIMICA ACTA
A novel application of a Pd(0)-catalyzed nucleophilic substitution reaction to the regio- and stereoselective synthesis of lactam analogues of the epothilone natural products
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Palladium-catalyzed enantioselective synthesis of carbanucleosides
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Enantioselective construction of quaternary alpha-carbon centers on alpha-amino phosphonates via catalytic asymmetric allylation
ORGANIC LETTERS
On the influence of the bite angle of bidentate phosphane ligands on the regioselectivity in allylic alkylation
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Asymmetric catalysis, 125 - Synthesis of the stereoisomers of methohexitalby palladium-catalyzed allylation
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Palladium-catalyzed enantioselective organic transformations
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Molten salts (ionic liquids) to improve the activity, selectivity and stability of the palladium catalysed Trost-Tsuji C-C coupling in biphasic media
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Robust and catalytically active mono- and bis-Pd-complexes of the 'Trost modular ligand'
CHEMICAL COMMUNICATIONS
A new class of C-2-symmetric diphosphine ligands derived from valine: remarkably diverse behavior in catalytic asymmetric transformations
TETRAHEDRON-ASYMMETRY
Chiral ferrocene derivatives containing a 2,2 '-bridged binaphthyl moiety
TETRAHEDRON-ASYMMETRY
The preparation and resolution of 2-phenyl-Quinazolinap, a new atropisomeric phosphinamine ligand for asymmetric catalysis
TETRAHEDRON-ASYMMETRY
A solvated transition state for the nucleophilic attack on cationic eta(3)-allylpalladium complexes
CHEMISTRY-A EUROPEAN JOURNAL
Novel axial chiral sulfur-oxazoline ligands with a biphenyl backbone
SYNLETT