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Titolo:
Total synthesis of (+/-)-smenospondiol by titanium(III)-mediated tandem radical cyclization
Autore:
Haruo, Y; Hasegawa, T; Tanaka, H; Takahashi, T;
Indirizzi:
Tokyo Inst Technol, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan Tokyo Inst Technol Tokyo Japan 1528552 , Meguro Ku, Tokyo 1528552, Japan
Titolo Testata:
SYNLETT
fascicolo: 12, , anno: 2001,
pagine: 1935 - 1937
SICI:
0936-5214(200112):12<1935:TSO(BT>2.0.ZU;2-A
Fonte:
ISI
Lingua:
ENG
Soggetto:
ORGANIC-SYNTHESIS; EPOXIDES; AVAROL; (-)-ILIMAQUINONE; HYDROGENATION; QUINONE; SPONGE; VIRUS;
Keywords:
tandem radical cyclizations; titanium; sesquiterpene hydroquinones; smenospondiol; drimane skeletons;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
32
Recensione:
Indirizzi per estratti:
Indirizzo: Takahashi, T Tokyo Inst Technol, Dept Appl Chem, Meguro Ku, Tokyo 1528552,Japan Tokyo Inst Technol Tokyo Japan 1528552 Tokyo 1528552, Japan
Citazione:
Y. Haruo et al., "Total synthesis of (+/-)-smenospondiol by titanium(III)-mediated tandem radical cyclization", SYNLETT, (12), 2001, pp. 1935-1937

Abstract

We describe the total synthesis of (+/-)-smenospondiol(1). Stereoselectiveconstruction of the drimane skeleton was accomplished by titanium (III)-mediated tandem radical cyclization of epoxide 9. Non-polar solvent is essential for the success of the tandem cyclization.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 09/07/20 alle ore 12:41:33