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Titolo:
Dinuclear pentamethylcyclopentadienyl rhodium and iridium complexes from C=C-bridged amino acid dimers - Metal complexes of biologically important ligands, CXXXIV.
Autore:
Dialer, H; Schumann, S; Polborn, K; Steglich, W; Beck, W;
Indirizzi:
Univ Munich, Dept Chem, D-81377 Munich, Germany Univ Munich Munich Germany D-81377 h, Dept Chem, D-81377 Munich, Germany
Titolo Testata:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
fascicolo: 7, , anno: 2001,
pagine: 1675 - 1679
SICI:
1434-1948(200107):7<1675:DPRAIC>2.0.ZU;2-E
Fonte:
ISI
Lingua:
ENG
Soggetto:
DIPEPTIDES;
Keywords:
rhodium; iridium; amino acids; amides; N,O ligands;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
14
Recensione:
Indirizzi per estratti:
Indirizzo: Steglich, W Univ Munich, Dept Chem, Butenandtstr 9-13, D-81377 Munich, Germany Univ Munich Butenandtstr 9-13 Munich Germany D-81377 Germany
Citazione:
H. Dialer et al., "Dinuclear pentamethylcyclopentadienyl rhodium and iridium complexes from C=C-bridged amino acid dimers - Metal complexes of biologically important ligands, CXXXIV.", EUR J INORG, (7), 2001, pp. 1675-1679

Abstract

Hippuric acid dimers bridged by a C=C double bond react with the chloro-bridged complexes (Cp*)(Cl)M(mu -Cl) M-2(Cp*)-(Cl) with decarboxylation or loss of a benzoyl group to give the unexpected ligand-bridged dinuclear complexes 2 and 4, which were characterized by X-ray diffraction. In the iridiumcomplex 2 an oxazolone derivative forms a C,O-N,N'-coordinated bridge, whereas in the rhodium complex 4 a chlorine atom and an amide group bridge thetwo metal atoms.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 27/09/20 alle ore 12:57:39