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Titolo:
Interlayer formation of cyclobis(paraquat-o-phenylene) by the reaction of laponite-4,4 '-bipyridinium intercalates with alpha, alpha '-dibromo-o-xylene: A one electron template synthesis
Autore:
Bourlinos, AB; Petridis, D;
Indirizzi:
NCSR Demokritos Ag Paraskevi Attikus, Inst Mat Sci, Athens 15310, Greece NCSR Demokritos Ag Paraskevi Attikus Athens Greece 15310 s 15310, Greece
Titolo Testata:
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
fascicolo: 1-2, volume: 40, anno: 2001,
pagine: 147 - 151
SICI:
1388-3127(200106)40:1-2<147:IFOCBT>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
RECEPTOR;
Keywords:
cyclophane; electron template synthesis; Laponite; radical;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
10
Recensione:
Indirizzi per estratti:
Indirizzo: Petridis, D NCSR Demokritos Ag Paraskevi Attikus, Inst Mat Sci, Athens 15310, Greece NCSR Demokritos Ag Paraskevi Attikus Athens Greece 15310 ece
Citazione:
A.B. Bourlinos e D. Petridis, "Interlayer formation of cyclobis(paraquat-o-phenylene) by the reaction of laponite-4,4 '-bipyridinium intercalates with alpha, alpha '-dibromo-o-xylene: A one electron template synthesis", J INCL P MA, 40(1-2), 2001, pp. 147-151

Abstract

Cyclobis(paraquat-o-phenylene) cyclophane can be synthesised in the form of a free radical within the gallery space of a synthetic aluminosilicate clay mineral. The interlayer formation of the cyclophane was revealed by XRD,IR and optical measurements. The mechanism of its formation is consistent with a one electron redox synthesis in which the electron donated by the clay mineral plays the role of the template towards the pi -electron deficient bipyridinium moieties.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/03/20 alle ore 12:42:52