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Titolo:
Synthesis and properties of optically active 1,1 ': 5 ',1 '': 5 '',1 '''-quaternaphthalene-2,2 ',6 ',2 '',6 '',2 '''-hexol (QUANOL)
Autore:
Sugimura, T; Kurita, SY; Inoue, S; Fujita, M; Okuyama, T; Tai, A;
Indirizzi:
Himeji Inst Technol, Fac Sci, Kamigori, Hyogo 6781297, Japan Himeji Inst Technol Kamigori Hyogo Japan 6781297 ri, Hyogo 6781297, Japan
Titolo Testata:
ENANTIOMER
fascicolo: 1, volume: 6, anno: 2001,
pagine: 35 - 42
SICI:
1024-2430(2001)6:1<35:SAPOOA>2.0.ZU;2-0
Fonte:
ISI
Lingua:
ENG
Soggetto:
DERIVATIVES; OLIGOMERS;
Keywords:
QUANOL; axial chirality; bidentate; higher homologue of BINOL; CD spectrum; redox property;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
19
Recensione:
Indirizzi per estratti:
Indirizzo: Sugimura, T Himeji Inst Technol, Fac Sci, Kamigori, Hyogo 6781297, Japan Himeji Inst Technol Kamigori Hyogo Japan 6781297 81297, Japan
Citazione:
T. Sugimura et al., "Synthesis and properties of optically active 1,1 ': 5 ',1 '': 5 '',1 '''-quaternaphthalene-2,2 ',6 ',2 '',6 '',2 '''-hexol (QUANOL)", ENANTIOMER, 6(1), 2001, pp. 35-42

Abstract

Optically active (R,R,R)- and (R,S,R)-1,1':5',1" :5",1"'-quaternaphthalene-2,2',6',2",6",2" '-hexol (QUANOL) were prepared from (R)-BINOL in five steps. The CD spectrum of (R,R,R)-QUANOL showed a larger A value than those of(R)-BINOL and (R,S,R)-QUANOL, but additivity of the axial chiralities in the A value was not observed. Other basic properties for the use of QUANOL as a chiral ligand are also reported.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 02/12/20 alle ore 08:06:48