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Titolo:
Engineering chiral catalysts through asymmetric activation and super high throughput screening (SHTS)
Autore:
Mikami, K; Korenaga, T; Matsukawa, S; Ding, KL; Long, J;
Indirizzi:
Tokyo Inst Technol, Fac Engn, Dept Appl Chem, Meguro Ku, Tokyo 152, Japan Tokyo Inst Technol Tokyo Japan 152 ppl Chem, Meguro Ku, Tokyo 152, Japan Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China Chinese Acad Sci Shanghai Peoples R China 200032 200032, Peoples R China
Titolo Testata:
CHINESE JOURNAL OF CHEMISTRY
fascicolo: 6, volume: 19, anno: 2001,
pagine: 545 - 557
SICI:
1001-604X(200106)19:6<545:ECCTAA>2.0.ZU;2-5
Fonte:
ISI
Lingua:
ENG
Soggetto:
ENANTIOMER-SELECTIVE ACTIVATION; ENANTIOSELECTIVE ADDITION; TITANIUM COMPLEX; ENE REACTION; ALDEHYDES; AMPLIFICATION; HYDROGENATION; DIALKYLZINCS; DIETHYLZINC; RESOLUTION;
Keywords:
chirality; asymmetric catalysis; asymmetric activation; asymmetric deactivation; high throughput screening;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
48
Recensione:
Indirizzi per estratti:
Indirizzo: Mikami, K Tokyo Inst Technol, Fac Engn, Dept Appl Chem, Meguro Ku, 2-12-1 Ookayama, Tokyo 152, Japan Tokyo Inst Technol 2-12-1 Ookayama Tokyo Japan 152 o 152, Japan
Citazione:
K. Mikami et al., "Engineering chiral catalysts through asymmetric activation and super high throughput screening (SHTS)", CHIN J CHEM, 19(6), 2001, pp. 545-557

Abstract

A conceptually new strategy for asymmetric catalysis, namely asymmetric activation, in which a chiral activator selectively activates one enantiomer of a racemic chiral catalyst, and a highly efficient screening system for finding the most effective catalysts, namely super high throughput screening(SHTS), by which the reaction can be conducted in parallel and the ee% of the product is allowed to determine within minutes, are summarized in the present account. It is reasonable to believe that SHTS technique combined with asymmetric activation or deactivation principle will provide a very powerful methodology for finding the new catalysts and the best catalyst tuningfor asymmetric reactions.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/04/20 alle ore 07:31:01