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Titolo:
Electronic and infrared spectra of jet-cooled 4-aminobenzonitrile-H2O. Change of NH2 from proton acceptor to proton donor by CN substitution
Autore:
Sakota, K; Yamamoto, N; Ohashi, K; Sekiya, H; Saeki, M; Ishiuchi, S; Sakai, M; Fujii, M;
Indirizzi:
Kyushu Univ, Grad Sch Mol Chem, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan Kyushu Univ Fukuoka Japan 8128581 em, Higashi Ku, Fukuoka 8128581, Japan Inst Mol Sci, Okazaki, Aichi 4448585, Japan Inst Mol Sci Okazaki Aichi Japan 4448585 i, Okazaki, Aichi 4448585, Japan Grad Univ Adv Studies, Sch Math & Phys Sci, Dept Funct Mol Sci, Okazaki, Aichi 4448585, Japan Grad Univ Adv Studies Okazaki Aichi Japan 4448585 i, Aichi 4448585, Japan
Titolo Testata:
CHEMICAL PHYSICS LETTERS
fascicolo: 1-2, volume: 341, anno: 2001,
pagine: 70 - 76
SICI:
0009-2614(20010615)341:1-2<70:EAISOJ>2.0.ZU;2-0
Fonte:
ISI
Lingua:
ENG
Soggetto:
LASER-INDUCED FLUORESCENCE; SUPERSONIC JET; VANDERWAALS COMPLEXES; SPECTROSCOPY; CLUSTERS; STATE; DYNAMICS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
20
Recensione:
Indirizzi per estratti:
Indirizzo: Sekiya, H Kyushu Univ, Grad Sch Mol Chem, Dept Chem, Higashi Ku, 6-10-1 Hakozaki, Fukuoka 8128581, Japan Kyushu Univ 6-10-1 Hakozaki Fukuoka Japan 8128581 128581, Japan
Citazione:
K. Sakota et al., "Electronic and infrared spectra of jet-cooled 4-aminobenzonitrile-H2O. Change of NH2 from proton acceptor to proton donor by CN substitution", CHEM P LETT, 341(1-2), 2001, pp. 70-76

Abstract

The electronic and infrared spectra of jet-cooled 4-aminobenzonitrile-(H2O)(I) (4ABN-(H2O)(I)) hydrogen-bonded complex have been measured by the resonance-enhanced multiphoton ionization (REMPI) and infrared-dip (IR-dip) spectroscopy. Both the amino and cyano groups form intermolecular hydrogen bond with water, providing two stable isomers. It has been found that the substitution of the CN group at the para-position of aniline changes the electronic nature of the amino group in the So state from a proton acceptor to a proton donor. (C) 2001 Elsevier Science B,V, All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 20/10/20 alle ore 05:57:44