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Titolo:
Palladium-catalysed asymmetric allylic alkylation in the presence of a chiral 'light fluorous' phosphine ligand
Autore:
Cavazzini, M; Pozzi, G; Quici, S; Maillard, D; Sinou, D;
Indirizzi:
CNR, Ctr Sintesi & Stereochim Speciali Sistemi Organ, I-20133 Milan, ItalyCNR Milan Italy I-20133 him Speciali Sistemi Organ, I-20133 Milan, Italy Univ Lyon 1, Lab Synth Asymetr, CNRS, UMR 5622, F-69622 Villeurbanne, France Univ Lyon 1 Villeurbanne France F-69622 22, F-69622 Villeurbanne, France
Titolo Testata:
CHEMICAL COMMUNICATIONS
fascicolo: 13, , anno: 2001,
pagine: 1220 - 1221
SICI:
1359-7345(2001):13<1220:PAAAIT>2.0.ZU;2-D
Fonte:
ISI
Lingua:
ENG
Soggetto:
SUPERCRITICAL CARBON-DIOXIDE; HYDROFORMYLATION; HYDROGENATION; SEPARATION; COMPLEXES; STRATEGY; SOLVENTS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
17
Recensione:
Indirizzi per estratti:
Indirizzo: Pozzi, G CNR, Ctr Sintesi & Stereochim Speciali Sistemi Organ, Via Golgi 19, I-20133 Milan, Italy CNR Via Golgi 19 Milan Italy I-20133 gi 19, I-20133 Milan, Italy
Citazione:
M. Cavazzini et al., "Palladium-catalysed asymmetric allylic alkylation in the presence of a chiral 'light fluorous' phosphine ligand", CHEM COMMUN, (13), 2001, pp. 1220-1221

Abstract

The easily accessible, enantiopure (R)-(+)-2-diarylphosphino-2'-alkoxy-1,1'-binaphthyl 1 bearing three fluorous ponytails is an efficient ligand in the palladium-catalysed asymmetric allylic substitution of 1,3-diphenylprop-2-enyl acetate affording chiral products of up to 87% ee.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/11/20 alle ore 16:36:47