Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Photofragment translational spectroscopy of weakly bound complexes: Probing the interfragment correlated final state distributions
Autore:
Oudejans, L; Miller, RE;
Indirizzi:
Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA Univ N Carolina Chapel Hill NC USA 27599 Chem, Chapel Hill, NC 27599 USA
Titolo Testata:
ANNUAL REVIEW OF PHYSICAL CHEMISTRY
, volume: 52, anno: 2001,
pagine: 607 - 637
SICI:
0066-426X(2001)52:<607:PTSOWB>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
HYDROGEN-FLUORIDE DIMER; INTRAMOLECULAR VIBRATIONAL REDISTRIBUTION; 6-DIMENSIONAL QUANTUM CALCULATIONS; INFRARED LASER SPECTROSCOPY; POTENTIAL-ENERGY SURFACE; HF BINARY COMPLEX; HCL DIMER; PREDISSOCIATION DYNAMICS; PHOTODISSOCIATION DYNAMICS; INTERMOLECULAR FORCES;
Keywords:
vibrational predissociation dynamics; dissociation energy;
Tipo documento:
Review
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
100
Recensione:
Indirizzi per estratti:
Indirizzo: Oudejans, L Univ N Carolina, Dept Chem, CB 3290, Chapel Hill, NC 27599 USAUniv N Carolina CB 3290 Chapel Hill NC USA 27599 NC 27599 USA
Citazione:
L. Oudejans e R.E. Miller, "Photofragment translational spectroscopy of weakly bound complexes: Probing the interfragment correlated final state distributions", ANN R PH CH, 52, 2001, pp. 607-637

Abstract

The vibrational predissociation dynamics of weakly bound complexes is wellknown to be highly nonstatistical. In particular, the associated photofragment final state distributions are often far from statistical, consequentlyreflecting the nature of the dissociation process. For binary complexes consisting of two molecules, a complete description of the final state of thesystem must include the associated interfragment correlations, specifically between their internal states. Information of this type is imprinted in the translational energies of the fragments, which can be measured using a number of recently developed translational spectroscopy methods. These data can provide detailed insights into the nature of the bond rupture process, as well as accurate Values for the dissociation energy of the complexes. The focus of the present review is on experiments that provide correlated final state distributions for weakly bound binary complexes. Where possible, comparisons with theoretical calculations are made.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 06/07/20 alle ore 05:56:23