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Titolo:
Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins
Autore:
Gomis, A; Net, G; Ruiz, A; Claver, C; Alvarez-Larena, A;
Indirizzi:
Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain Univ Rovira & Virgili Tarragona Spain 43005 rgan, Tarragona 43005, Spain Univ Autonoma Barcelona, Area Cristallog & Mineral, E-08193 Barcelona, Spain Univ Autonoma Barcelona Barcelona Spain E-08193 E-08193 Barcelona, Spain
Titolo Testata:
INORGANICA CHIMICA ACTA
fascicolo: 1-2, volume: 325, anno: 2001,
pagine: 58 - 64
SICI:
0020-1693(200112)325:1-2<58:RAIDCA>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Soggetto:
CATIONIC IRIDIUM(I) COMPLEXES; ASYMMETRIC HYDROGENATION; RHODIUM COMPLEXES; CATALYST PRECURSORS; METAL-COMPLEXES; CHIRAL LIGANDS; SULFUR-DONOR; HYDROFORMYLATION; REACTIVITY;
Keywords:
S-ligands; rhodium and iridium complexes; dithioether complexes; hydrogenation of olefins;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
38
Recensione:
Indirizzi per estratti:
Indirizzo: Claver, C Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Placa Imperial Tarraco 1, Tarragona 43005, Spain Univ Rovira & Virgili Placa Imperial Tarraco 1 Tarragona Spain 43005
Citazione:
A. Gomis et al., "Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins", INORG CHIM, 325(1-2), 2001, pp. 58-64

Abstract

Mononuclear complexes [M(cod)(RS(CH2)(n)SR)]BF4 (M = Rh, Ir; n = 2-4)) were synthesized and characterized. The crystal structure of [Rh(cod){(CH3)(2)CHS(CH2)(4)SCH(CH3)(2)}]BF4 was determined by X-ray diffraction. The iridium complexes are catalytically active precursors in the hydrogenation of olefins. The effect of the length of the backbone between the two sulfur atomsand the group R bonded to sulfur was studied in the hydrogenation of itaconic acid and 1-hexene. (C) 2001 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 05/12/20 alle ore 10:38:38