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Titolo:
One-dimensional copper-pyridinedicarboxylate polymer containing square-planar Cu(II) centers exhibiting antiferromagnetic coupling
Autore:
Min, DW; Yoon, SS; Jung, DY; Lee, CY; Kim, Y; Han, WS; Lee, SW;
Indirizzi:
Sung Kyun Kwan Univ, Dept Chem, Suwon 440746, South Korea Sung Kyun Kwan Univ Suwon South Korea 440746 , Suwon 440746, South Korea Sung Kyun Kwan Univ, Sch Mol Sci BK21, Suwon 440746, South Korea Sung KyunKwan Univ Suwon South Korea 440746 , Suwon 440746, South Korea
Titolo Testata:
INORGANICA CHIMICA ACTA
fascicolo: 1-2, volume: 324, anno: 2001,
pagine: 293 - 299
SICI:
0020-1693(20011112)324:1-2<293:OCPCS>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
COORDINATION CHEMISTRY; CRYSTAL-STRUCTURES; NETWORKS; COMPLEXES; LIGANDS; DESIGN;
Keywords:
one-dimensional coordination polymers; antiferromagnetic coupling;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
35
Recensione:
Indirizzi per estratti:
Indirizzo: Lee, SW Sung Kyun Kwan Univ, Dept Chem, Nat Sci Campus, Suwon 440746, South Korea Sung Kyun Kwan Univ Nat Sci Campus Suwon South Korea 440746 Korea
Citazione:
D.W. Min et al., "One-dimensional copper-pyridinedicarboxylate polymer containing square-planar Cu(II) centers exhibiting antiferromagnetic coupling", INORG CHIM, 324(1-2), 2001, pp. 293-299

Abstract

The hydrothermal reaction of Cu(NO3)(2).2.5H(2)O with 2,5-pyridinedicarboxylic acid (2,5-PDCH2) led to the formation of a one-dimensional coordination polymer with the empirical formula of Cu(2,5-PDC)(H2O) (1). On the other hand, the hydrothermal reaction of Cu(NO3)(2).2.5H(2)O with 2,4-pyridinedicarboxylic acid (2,4-PDCH2) gave a mononuclear Cu(II) compound Cu(2,4-PDC)(2) (2). The structures of both compounds have been determined by X-ray diffraction. In both compounds, the coordination sphere of the Cu metal is square-planar. The polymer 1 exhibits strong antiferromagnetic coupling between the paramagnetic Cu(II) metals in the adjacent layers even in the absence of intervening groups. (C) 2001 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 27/11/20 alle ore 16:13:16