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Titolo:
Chiral complexes by direct synthesis of a biomolecule and metal powders. Crystal structures of the dichloro[(-)-sparteine-N,N ']M(II) complexes (M = Cu, Zn)
Autore:
Gutierrez, R; Vazquez, J; Vazquez, RA; Reyes, Y; Toscano, RA; Martinez, M; Alvarez, C;
Indirizzi:
Natl Autonomous Univ Mexico, Inst Quim, Mexico City 04510, DF, Mexico NatlAutonomous Univ Mexico Mexico City DF Mexico 04510 04510, DF, Mexico Univ Autonoma Puebla, Fac Ciencias Quim, Ctr Invest, Puebla 72001, Mexico Univ Autonoma Puebla Puebla Mexico 72001 tr Invest, Puebla 72001, Mexico Univ Autonoma Puebla, Inst Ciencias, Ctr Invest, Puebla 72001, Mexico UnivAutonoma Puebla Puebla Mexico 72001 tr Invest, Puebla 72001, Mexico
Titolo Testata:
JOURNAL OF COORDINATION CHEMISTRY
fascicolo: 3-4, volume: 54, anno: 2001,
pagine: 313 - 321
SICI:
0095-8972(2001)54:3-4<313:CCBDSO>2.0.ZU;2-9
Fonte:
ISI
Lingua:
ENG
Soggetto:
MOLECULAR-STRUCTURE; (-)-SPARTEINE; PERCHLORATE;
Keywords:
direct synthesis; chiral complexes; (-)-sparteine;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
31
Recensione:
Indirizzi per estratti:
Indirizzo: Alvarez, C Natl Autonomous Univ Mexico, Inst Quim, Circuito Exterior,Ciudad Univ, Mexico City 04510, DF, Mexico Natl Autonomous Univ Mexico Circuito Exterior,Ciudad Univ Mexico City DF Mexico 04510
Citazione:
R. Gutierrez et al., "Chiral complexes by direct synthesis of a biomolecule and metal powders. Crystal structures of the dichloro[(-)-sparteine-N,N ']M(II) complexes (M = Cu, Zn)", J COORD CH, 54(3-4), 2001, pp. 313-321

Abstract

Direct synthesis of chiral complexes dichloro[(-)-sparteine-N,N']copper(II) 2 and dichloro[(-)sparteine-N,N']zinc(II) 3 derived from a biomolecule-namely the natural base (-)-sparteine- and elemental metals (Cu and Zn) in a CCl4/DMSO solvent system (DMSO = dimethylsulfoxide) is reported. The complexes were partly characterized by spectroscopic methods and their structureswere fully confirmed by single-crystal x-ray analysis. A comparison between the new crystal structures of 2 and 3 and that of the free ligand (-)-sparteine displayed only slight differences on the ligand framework.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 23/01/20 alle ore 03:32:02