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Titolo:
Cd-113 MAS and static NMR study of halogenocadmate crystals
Autore:
Sakida, S; Kawamoto, Y;
Indirizzi:
Kobe Univ, Venture Business Lab, Kobe, Hyogo 6578501, Japan Kobe Univ Kobe Hyogo Japan 6578501 siness Lab, Kobe, Hyogo 6578501, Japan Kobe Univ, Grad Sch Sci & Technol, Div Mol Sci, Kobe, Hyogo 6578501, JapanKobe Univ Kobe Hyogo Japan 6578501 iv Mol Sci, Kobe, Hyogo 6578501, Japan
Titolo Testata:
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
fascicolo: 1, volume: 63, anno: 2002,
pagine: 151 - 161
SICI:
0022-3697(200201)63:1<151:CMASNS>2.0.ZU;2-C
Fonte:
ISI
Lingua:
ENG
Keywords:
inorganic compounds; nuclear magnetic resonance (NMR);
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
29
Recensione:
Indirizzi per estratti:
Indirizzo: Sakida, S Kobe Univ, Venture Business Lab, Kobe, Hyogo 6578501, Japan KobeUniv Kobe Hyogo Japan 6578501 , Kobe, Hyogo 6578501, Japan
Citazione:
S. Sakida e Y. Kawamoto, "Cd-113 MAS and static NMR study of halogenocadmate crystals", J PHYS CH S, 63(1), 2002, pp. 151-161

Abstract

Cd-113 magic-angle spinning (MAS) and static NMR spectra are measured using 23 kinds of halogenocadmate crystals with known structures to determine the isotropic chemical shifts (delta (iso)), chemical shift anisotropies (Delta delta), and asymmetry parameters eta and then to discuss the relationship among these NMR parameters and the halide-anion co-ordination environments around Cd2+. The delta (iso(MAS)) values of halide-anion co-ordination polyhedra of Cd2+ largely change with the kind of halide-anion and the halide-anion co-ordination number, The \ Delta delta \ and eta in halogenocadmate crystals is largely dependent on the structure type of crystal, but is independent of the halide-anion co-ordination number of Cd2+. (C) 2001 Elsevier Science Ltd. All rights reserved.

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Documento generato il 06/04/20 alle ore 01:49:45