Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Towards rational design and synthesis of aluminophosphates with 2-D layer and 3-D open-framework structures
Autore:
Yu, JH; Li, LY; Xu, RR;
Indirizzi:
Jilin Univ, State Key Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China Jilin Univ Changchun Peoples R China 130023 chun 130023, Peoples R China
Titolo Testata:
MICROPOROUS AND MESOPOROUS MATERIALS
fascicolo: 1-3, volume: 48, anno: 2001,
pagine: 47 - 56
SICI:
1387-1811(20011101)48:1-3<47:TRDASO>2.0.ZU;2-7
Fonte:
ISI
Lingua:
ENG
Soggetto:
ANIONIC ALUMINOPHOSPHATES; ALUMINUM PHOSPHATE; STOICHIOMETRY; DIVERSITY; TOPOLOGY; TEMPLATE;
Keywords:
aluminophosphates; design; rational synthesis; computer modeling and simulation;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
22
Recensione:
Indirizzi per estratti:
Indirizzo: Xu, RR Jilin Univ, State Key Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China Jilin Univ Changchun Peoples R China 130023 0023, Peoples R China
Citazione:
J.H. Yu et al., "Towards rational design and synthesis of aluminophosphates with 2-D layer and 3-D open-framework structures", MICROP M M, 48(1-3), 2001, pp. 47-56

Abstract

This work presents our current progress on the rational design and synthesis of aluminophosphates with 2-D layer and 3-D open-framework structures. For the design of theoretical structures, we take two ways, one is using building block construction strategy to construct new 2-D networks and 3-D open frameworks. The other is using computer modeling method to systematicallyenumerate the theoretical network structures. The templating abilities of various amines in the formation of 2-D network or 3-D open-framework aluminophosphates can be evaluated in terms of nonbonding interaction energies ofthe guest templates and the host inorganic networks or frameworks. This well assists in the rational synthesis of target materials, with the good examples as 2-D Al3P4O163- anionic layers, and 3-D Al4P5O19(OH)(2-) open frameworks with structures analogous to AlPO-HDA (HDA: 1,6-hexanediamine). On the other hand, 3-D open framework can be rationally assembled by a lower-dimensional chain through incorporation of transition metal cations as illustrated by the successful synthesis of a 3-D open-framework nickel aluminophosphate [NiAlP2O8][C2N2H9]. (C) 2001 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/03/20 alle ore 23:13:33