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Titolo:
Synthesis and chemistry of the 16-electron osmium complex [OsBr(eta(5)-C5Me5)(PiPr(3))]
Autore:
Glaser, PB; Tilley, TD;
Indirizzi:
Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA Univ Calif Berkeley Berkeley CA USA 94720 pt Chem, Berkeley, CA 94720 USA
Titolo Testata:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
fascicolo: 11, , anno: 2001,
pagine: 2747 - 2750
SICI:
1434-1948(200111):11<2747:SACOT1>2.0.ZU;2-6
Fonte:
ISI
Lingua:
ENG
Soggetto:
NUCLEAR MAGNETIC-RESONANCE; RAY CRYSTAL-STRUCTURE; SPECTROSCOPY; DERIVATIVES; PRECURSOR; CL;
Keywords:
osmium; cyclopentadienyl ligands; oxidative addition; coordinative unsaturation;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
17
Recensione:
Indirizzi per estratti:
Indirizzo: Tilley, TD Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA Univ Calif Berkeley Berkeley CA USA 94720 rkeley, CA 94720 USA
Citazione:
P.B. Glaser e T.D. Tilley, "Synthesis and chemistry of the 16-electron osmium complex [OsBr(eta(5)-C5Me5)(PiPr(3))]", EUR J INORG, (11), 2001, pp. 2747-2750

Abstract

The isolable 16-electron half-sandwich Cls complex [OsBr(eta (C5Me5)-C-5)(PiPr(3))] has been synthesized and structurally characterized. This unsaturated complex binds N-2 reversibly at low temperature as determined by IR and multinuclear NMR spectroscopy. The reactions of the title complex with CO, H-2, PhSiH3, and its thermolysis in C6H6 are reported.

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Documento generato il 05/04/20 alle ore 03:28:47