Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Synthesis and crystal structure of the complex of thioglycollic acid and trivalent antimony ion
Autore:
Zhong, GQ; Guo, YC; Chen, YR; Zang, XS; Luan, SR;
Indirizzi:
Sichuan Inst Anim Husb & Vet Med, Dept Basic Sci, Chongqing 402460, Peoples R China Sichuan Inst Anim Husb & Vet Med Chongqing Peoples R China 402460 China Nanyang Teachers Coll, Dept Chem, Henan 473061, Peoples R China Nanyang Teachers Coll Henan Peoples R China 473061 3061, Peoples R China E China Univ Sci & Technol, Dept Chem, Shanghai 200237, Peoples R China E China Univ Sci & Technol Shanghai Peoples R China 200237 oples R China
Titolo Testata:
ACTA CHIMICA SINICA
fascicolo: 10, volume: 59, anno: 2001,
pagine: 1599 - 1603
SICI:
0567-7351(2001)59:10<1599:SACSOT>2.0.ZU;2-C
Fonte:
ISI
Lingua:
CHI
Soggetto:
DERIVATIVES;
Keywords:
complex of antimony(III) and thioglycollic acid; synthesis; single crystal structure; indexes of X-ray powder diffraction data;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
12
Recensione:
Indirizzi per estratti:
Indirizzo: Zhong, GQ Sichuan Inst Anim Husb & Vet Med, Dept Basic Sci, Chongqing 402460, Peoples R China Sichuan Inst Anim Husb & Vet Med Chongqing Peoples R China 402460
Citazione:
G.Q. Zhong et al., "Synthesis and crystal structure of the complex of thioglycollic acid and trivalent antimony ion", ACT CHIM S, 59(10), 2001, pp. 1599-1603

Abstract

The solid complex of HSb (SCH2COO)(2) was synthesized through a reaction between antimony trioxide and thioglycollic acid in the aqueous solution. The complex was characterized with elemental analyses, infrared spectra, X - ray powder diffraction and X - ray crystal structure. The crystal structureof the complex belongs to monoclinic system, space group C2/c, with lattice parameters: a = 1.40005(8) nm, b = 1.19121 (8) nm, c = 1.23588(8) nm, beta = 126.822(1), V = 1.6499(2) nm(3), D-c = 2.439 g(.)cm(-3), Z = 8 and R-1 = 0.0250. The antimony ion bonds directly to the sulfur atom of the thiohydroxy - group and the oxygen atom of the carboxyl - group. There is not onlythe hydrogen bond of intermolecule, but also the coordination bonds of theantimony ion - sulfur or - oxygen atom of intermolecule. The results of indexes to the X - ray powder diffraction data for the complex are consistentwith the results of single crystal.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/03/20 alle ore 10:00:06