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Titolo:
Synthesis and polymerization of new styryl and methacryloyl monomers containing acidic saccharide moieties
Autore:
Shimura, Y; Hashimoto, K; Yamanaka, C; Setojima, D;
Indirizzi:
Kogakuin Univ, Fac Engn, Dept Appl Chem, Hachioji, Tokyo 1920015, Japan Kogakuin Univ Hachioji Tokyo Japan 1920015 Hachioji, Tokyo 1920015, Japan
Titolo Testata:
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
fascicolo: 22, volume: 39, anno: 2001,
pagine: 3893 - 3901
SICI:
0887-624X(20011115)39:22<3893:SAPONS>2.0.ZU;2-T
Fonte:
ISI
Lingua:
ENG
Soggetto:
L-LYSINE-DERIVATIVES; ANIONIC-POLYMERIZATION; BICYCLIC OXALACTAM; POLYAMIDE; BEHAVIOR; RELEASE; GLYCOL); LACTAM;
Keywords:
glycopolymer; D-glucuronic acid; glycomonomer; radical polymerization; isopropylidene group; deprotection; biomaterials; hydrophilic polymers;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
23
Recensione:
Indirizzi per estratti:
Indirizzo: Hashimoto, K Kogakuin Univ, Fac Engn, Dept Appl Chem, Nakano Cho, Hachioji, Tokyo 1920015, Japan Kogakuin Univ Nakano Cho Hachioji Tokyo Japan 1920015 , Japan
Citazione:
Y. Shimura et al., "Synthesis and polymerization of new styryl and methacryloyl monomers containing acidic saccharide moieties", J POL SC PC, 39(22), 2001, pp. 3893-3901

Abstract

New styryl-type water-insoluble and methacryloyl-type water-soluble monomers, N-(p-vinylbenzyl)-1,2-O-isopropylidene-6-D-glucofuranuronamide and N-(2-methacryloylamino)ethyl-1,2-O-isopropylidene-6-D-glucofuranuronamide, weresynthesized from the most common acidic saccharide, D-glucuronic acid. Their radical homopolymerizations and copolymerizations with styrene and acrylamide were tried under various conditions. The isopropylidene groups in theresulting polymers were removed in a mixture of trifluoroacetic acid and water (2/1 v/v) to give the corresponding polymers with many pendant D-glucopyranuronyl groups with reactive reducing groups. The pendant reducing endsmay be useful as potential binding sites under a hydrophilic atmosphere. (C) 2001 John Wiley & Sons, Inc.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 08/04/20 alle ore 08:57:25