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Titolo:
Coordination chemistry of Fe+, (c-C5H5)Fe+, and (c-C5H5)(2)Fe+ in the gas phase at room temperature: kinetics of sequential ligation with hydrogen cyanide and cyanoacetylene
Autore:
Baranov, V; Bohme, DK;
Indirizzi:
York Univ, Ctr Res Mass Spectrometry, Dept Chem, N York, ON M3J 1P3, Canada York Univ N York ON Canada M3J 1P3 Dept Chem, N York, ON M3J 1P3, Canada York Univ, Ctr Res Earth & Space Sci, N York, ON M3J 1P3, Canada York Univ N York ON Canada M3J 1P3 Space Sci, N York, ON M3J 1P3, Canada
Titolo Testata:
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
fascicolo: 1-3, volume: 210, anno: 2001,
pagine: 303 - 310
SICI:
1387-3806(20011001)210:1-3<303:CCOF(A>2.0.ZU;2-1
Fonte:
ISI
Lingua:
ENG
Soggetto:
ION FLOW TUBE; INORGANIC LIGANDS; FEO+; MG+; TRANSITION; MOLECULE; IRON;
Keywords:
Fe+; (c-C5H5)Fe+; hydrogen cyanide; cyanoacetylene; gas-phase ligation kinetics; SIFT technique; CID technique;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
23
Recensione:
Indirizzi per estratti:
Indirizzo: Bohme, DK York Univ, Ctr Res Mass Spectrometry, Dept Chem, N York, ON M3J 1P3, Canada York Univ N York ON Canada M3J 1P3 , N York, ON M3J 1P3, Canada
Citazione:
V. Baranov e D.K. Bohme, "Coordination chemistry of Fe+, (c-C5H5)Fe+, and (c-C5H5)(2)Fe+ in the gas phase at room temperature: kinetics of sequential ligation with hydrogen cyanide and cyanoacetylene", INT J MASS, 210(1-3), 2001, pp. 303-310

Abstract

Measurements with the selected-ion flow tube technique are reported for the room-temperature kinetics of the sequential ligation of Fe+ and (c-C5H5)Fe+ with HCN and HC3N in helium bath gas at 0.35 Torr. (c-C5H5)(2)Fe+ was observed not to react. Titration curves of the variation in the apparent bimolecular rate coefficient for ligation with the number of ligands provide cyanide coordination numbers for Fe+ in the absence (4) and presence (3) of c-C5H5.. Multicollision induced dissociation experiments indicate the absence of intramolecular ligand-ligand interaction mediated by Fe+. (C) 2001 Elsevier Science B.V.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 23/09/20 alle ore 10:28:06