Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Selective electroless nickel plating on polyelectrolyte multilayer platforms
Autore:
Wang, TC; Chen, B; Rubner, MF; Cohen, RE;
Indirizzi:
MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA MIT Cambridge MA USA 02139 , Dept Mat Sci & Engn, Cambridge, MA 02139 USA MIT, Dept Chem Engn, Cambridge, MA 02139 USA MIT Cambridge MA USA 02139MIT, Dept Chem Engn, Cambridge, MA 02139 USA MIT, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA MIT Cambridge MA USA 02139 T, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA
Titolo Testata:
LANGMUIR
fascicolo: 21, volume: 17, anno: 2001,
pagine: 6610 - 6615
SICI:
0743-7463(20011016)17:21<6610:SENPOP>2.0.ZU;2-J
Fonte:
ISI
Lingua:
ENG
Soggetto:
POLYMER SURFACE MODIFICATION; BY-LAYER DEPOSITION; POLY(PHENYLENE VINYLENE); WEAK POLYELECTROLYTES; CONJUGATED POLYMERS; THIN-FILMS; DEVICES; COPPER; HETEROSTRUCTURES; FABRICATION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
55
Recensione:
Indirizzi per estratti:
Indirizzo: Rubner, MF MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA MIT Cambridge MA USA 02139 Sci & Engn, Cambridge, MA 02139 USA
Citazione:
T.C. Wang et al., "Selective electroless nickel plating on polyelectrolyte multilayer platforms", LANGMUIR, 17(21), 2001, pp. 6610-6615

Abstract

Polyelectrolyte multilayers (PEMs) fabricated by the layer-by-layer adsorption of poly(acrylic acid) (PAA) and poly(allylamine hydrochloride) (PAH) are used to selectively bind palladium catalysts for electroless nickel Plating. Depending on the PH conditions used during multilayer processing and the polyelectrolyte adsorbed last, the surface of the PAH/PAA-based multilayers can be tuned to contain primarily PAA, primarily PAH, or a mixture of PAA and PAR functionalities (i.e., carboxylic acids or amines). The palladium-complex ions of tetraaminepalladium chloride (Pd(NH3)(4)Cl-2) or sodium tetrachloropalladate (Na2PdCl4) bind selectively ky ion exchange only to surfaces of PAA or PAH, respectively. Substrates that are coated with regions of PAA-topped and PAH-topped multilayers, fabricated at a PAR PH of 7.5 anda PAA PH of 3.5, bind [Pd(NH3)(4)](2+) only on the PAA regions. Upon immersion into an electroless nickel plating bath, only the PAA-topped regions of the substrate, activated by the Pd complex, promote nickel plating while the PAH-topped regions resist plating. By using [PdCl4](2-), the PAR regions are selectively plated instead. Moreover, the facile patternability of PEMs is demonstrated using the inkjet printing of a PAA solution onto a PAR-topped multilayer film. Tetraaminepalladium ion binding and nickel plating are confined to the printed PAA pattern. Because of their surface tunable capabilities and therefore ease of selective activation, conformal coverage, facile processing, adherent coating, and patternability, PAH/PAA-based multilayers are ideal platforms for selective electroless plating.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/09/20 alle ore 00:04:11