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Titolo:
Photochemically induced electron transfer (PET) catalyzed radical cyclization: A practical method for inducing structural changes in peptides by formation of cyclic amino acid derivatives
Autore:
Jonas, M; Blechert, S; Steckhan, E;
Indirizzi:
Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany Tech Univ Berlin Berlin Germany D-10623 st Chem, D-10623 Berlin, Germany Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany Univ Bonn Bonn Germany D-53121 gan Chem & Biochem, D-53121 Bonn, Germany
Titolo Testata:
JOURNAL OF ORGANIC CHEMISTRY
fascicolo: 21, volume: 66, anno: 2001,
pagine: 6896 - 6904
SICI:
0022-3263(20011019)66:21<6896:PIET(C>2.0.ZU;2-J
Fonte:
ISI
Lingua:
ENG
Soggetto:
DIELS-ALDER REACTION; ACCEPTOR-SUBSTITUTED ENAMINES; SOLID-PHASE SYNTHESIS; CYCLOADDITION REACTIONS; PROTEINS; 2-VINYLINDOLES; METATHESIS; OXIDATION; DYNAMICS; CATIONS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
53
Recensione:
Indirizzi per estratti:
Indirizzo: Blechert, S Tech Univ Berlin, Inst Chem, Str 17 Juni 135, D-10623 Berlin, Germany Tech Univ Berlin Str 17 Juni 135 Berlin Germany D-10623 rmany
Citazione:
M. Jonas et al., "Photochemically induced electron transfer (PET) catalyzed radical cyclization: A practical method for inducing structural changes in peptides by formation of cyclic amino acid derivatives", J ORG CHEM, 66(21), 2001, pp. 6896-6904

Abstract

A new radical cyclization reaction of unsaturated amino acid derivatives is presented. The reaction is induced by photoelectron transfer (PET) catalysis and proceeds, in comparison to commonly applied methods, under mild, nonoxidizing, and nontoxic conditions in neutral medium. This type of radicalcyclization reaction can be used in peptide chemistry for inducing structural changes in peptides.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 06/12/20 alle ore 00:00:09