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Titolo:
Synthesis of triketide delta-lactones
Autore:
Kim, SJ; Kang, HY; Sherman, DH;
Indirizzi:
Chungbuk Natl Univ, Dept Chem, Cheongju 361763, Chungbuk, South Korea Chungbuk Natl Univ Cheongju Chungbuk South Korea 361763 gbuk, South Korea Univ Minnesota, Dept Microbiol, Minneapolis, MN 55455 USA Univ Minnesota Minneapolis MN USA 55455 robiol, Minneapolis, MN 55455 USA Univ Minnesota, Biol Proc Technol Inst, Minneapolis, MN 55455 USA Univ Minnesota Minneapolis MN USA 55455 l Inst, Minneapolis, MN 55455 USA
Titolo Testata:
SYNTHESIS-STUTTGART
fascicolo: 12, , anno: 2001,
pagine: 1790 - 1793
SICI:
0039-7881(200109):12<1790:SOTD>2.0.ZU;2-V
Fonte:
ISI
Lingua:
ENG
Soggetto:
MODULAR POLYKETIDE SYNTHASE; CHROMIUM(II)-MEDIATED REFORMATSKY REACTIONS; CHIRAL ALPHA-BROMOACETYL-2-OXAZOLIDINONES; ALDEHYDES; ACID; BIOSYNTHESIS; EXPRESSION; DOMAIN;
Keywords:
polyketide biosynthesis; lactones; samarium(II) iodide; aldol reaction; reformatsky reaction;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
21
Recensione:
Indirizzi per estratti:
Indirizzo: Kang, HY Chungbuk Natl Univ, Dept Chem, Cheongju 361763, Chungbuk, South Korea Chungbuk Natl Univ Cheongju Chungbuk South Korea 361763 th Korea
Citazione:
S.J. Kim et al., "Synthesis of triketide delta-lactones", SYNTHESIS-S, (12), 2001, pp. 1790-1793

Abstract

An efficient synthetic route was developed to prepare substituted delta -lactones 1 and 2 in enantiopure forms which are potentially useful for biosynthetic studies with genetically engineered modular polyketide synthase (PKS). The key step to prepare the target epimeric lactones involves the samarium(II) iodide-mediated Reformatsky reaction.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 03/12/20 alle ore 05:33:25