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Titolo:
SAFT1 for associating fluids: Alkanols
Autore:
Adidharma, H; Radosz, M;
Indirizzi:
Univ Wyoming, Dept Chem & Petr Engn, Laramie, WY 82071 USA Univ Wyoming Laramie WY USA 82071 Chem & Petr Engn, Laramie, WY 82071 USA
Titolo Testata:
JOURNAL OF PHYSICAL CHEMISTRY B
fascicolo: 40, volume: 105, anno: 2001,
pagine: 9822 - 9827
SICI:
1520-6106(20011011)105:40<9822:SFAFA>2.0.ZU;2-Q
Fonte:
ISI
Lingua:
ENG
Soggetto:
DIRECTIONAL ATTRACTIVE FORCES; THERMODYNAMIC PERTURBATION-THEORY; TELECHELIC POLYISOBUTYLENE PIB; HARD CHAIN MOLECULES; SQUARE-WELL FLUID; PHASE-EQUILIBRIA; INTRAMOLECULAR ASSOCIATION; SUPERCRITICAL FLUIDS; INTER-ASSOCIATION; CARBON-DIOXIDE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
35
Recensione:
Indirizzi per estratti:
Indirizzo: Radosz, M Univ Wyoming, Dept Chem & Petr Engn, Laramie, WY 82071 USA Univ Wyoming Laramie WY USA 82071 r Engn, Laramie, WY 82071 USA
Citazione:
H. Adidharma e M. Radosz, "SAFT1 for associating fluids: Alkanols", J PHYS CH B, 105(40), 2001, pp. 9822-9827

Abstract

The SAFT1 equation of state is extended using Wertheim's theory to model associating fluids and tested on pure alkanols and mixtures containing alkanols. For small 1-alkanols, SAFT1 is found to represent the vapor pressure and liquid density. The SAFT1 parameters are shown to be well-behaved and hence possible to estimate for high-molecular-weight 1-alkanols and hydroxy polymers on the basis of their molecular weight alone.

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Documento generato il 12/12/19 alle ore 10:14:48