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Titolo:
Chemistry, properties and applications of the assembling 1,8-diisocyano-p-menthane, 2,5-dimethyl-2 ',5 '-diisocyanohexane and 1,3-diisocyanopropane ligands and their coordination polynuclear complexes
Autore:
Harvey, PD;
Indirizzi:
Univ Sherbrooke, Dept Chim, Sherbrooke, PQ J1K 2R1, Canada Univ Sherbrooke Sherbrooke PQ Canada J1K 2R1 erbrooke, PQ J1K 2R1, Canada
Titolo Testata:
COORDINATION CHEMISTRY REVIEWS
, volume: 219, anno: 2001,
pagine: 17 - 52
SICI:
0010-8545(200109/10)219:<17:CPAAOT>2.0.ZU;2-I
Fonte:
ISI
Lingua:
ENG
Soggetto:
RHODIUM ISOCYANIDE COMPLEXES; RAY CRYSTAL-STRUCTURE; DMB = 1,8-DIISOCYANO-P-MENTHANE; ELECTRONIC EXCITED-STATES; SOLAR-ENERGY STORAGE; METAL-METAL INTERACTIONS; BINUCLEAR RHODIUM; FORCE-CONSTANTS; SPECTROSCOPIC CHARACTERIZATION; ORGANOMETALLIC MATERIALS;
Keywords:
isocyanides; bridging ligands; polynuclear complexes; polymeric materials;
Tipo documento:
Review
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
82
Recensione:
Indirizzi per estratti:
Indirizzo: Harvey, PD Univ Sherbrooke, Dept Chim, Sherbrooke, PQ J1K 2R1, Canada UnivSherbrooke Sherbrooke PQ Canada J1K 2R1 Q J1K 2R1, Canada
Citazione:
P.D. Harvey, "Chemistry, properties and applications of the assembling 1,8-diisocyano-p-menthane, 2,5-dimethyl-2 ',5 '-diisocyanohexane and 1,3-diisocyanopropane ligands and their coordination polynuclear complexes", COORD CH RE, 219, 2001, pp. 17-52

Abstract

This review article presents an overview of the coordination chemistry of the three title bridging ligands, along with some selected structural, vibrational and electronic spectroscopic, photo- and electrochemical, and catalytic properties. These ligands can bridge metal atoms to form bi-, tri, andtetranuclear complexes and polymers. Solid state properties for the polymeric materials such as glass transitions, intrachain exciton phenomena, semi- and photoconductivity, as well as the design of photovoltaic cells are briefly described. (C) 2001 Elsevier Science B.V. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/09/20 alle ore 22:57:35