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Titolo:
Difluorinated Danishefsky's diene: A versatile C-4 building block for the fluorinated six-membered rings
Autore:
Amil, H; Kobayashi, T; Terasawa, H; Uneyama, K;
Indirizzi:
Okayama Univ, Fac Engn, Dept Appl Chem, Okayama 7008530, Japan Okayama Univ Okayama Japan 7008530 ept Appl Chem, Okayama 7008530, Japan
Titolo Testata:
ORGANIC LETTERS
fascicolo: 20, volume: 3, anno: 2001,
pagine: 3103 - 3105
SICI:
1523-7060(20011004)3:20<3103:DDDAVC>2.0.ZU;2-Q
Fonte:
ISI
Lingua:
ENG
Soggetto:
DIELS-ALDER REACTIONS; F BOND-CLEAVAGE; TRIFLUOROMETHYL KETONES; ELECTROREDUCTIVE DEFLUORINATION; 2+2 CYCLOADDITIONS; DERIVATIVES; 1,1-DIFLUORO-2-TRIPHENYLSILOXYBUTA-1,3-DIENE; ALDEHYDES; ETHERS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
32
Recensione:
Indirizzi per estratti:
Indirizzo: Uneyama, K Okayama Univ, Fac Engn, Dept Appl Chem, 3-1-1 Tsushimanaka, Okayama 7008530, Japan Okayama Univ 3-1-1 Tsushimanaka Okayama Japan 7008530 0, Japan
Citazione:
H. Amil et al., "Difluorinated Danishefsky's diene: A versatile C-4 building block for the fluorinated six-membered rings", ORG LETT, 3(20), 2001, pp. 3103-3105

Abstract

[GRAPHICS]A Mg(0)/Me3SiCl system was found to be effective for the preparation of difluoro Danishefsky's dienes 2, which involves selective C-F bond cleavage of trifluoromethyl ketones 3. Subsequent hetero Diels-Alder reactions of 2 with aldehydes and imines gave a variety of fluorinated six-membered heterocycles.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 05/04/20 alle ore 13:24:25