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Titolo:
(-)(D)-aquabromo{3,3 '-[(1R,2R)-1,2-bis(2,4,6-trimethyl-phenyl)ethane-1,2-diylbis(nitrilomethylidyne)]bis-(pentane-2,4-dionato)-N,N ',O,O '}cobalt(III) tetrahydrofuran solvate
Autore:
Ohba, S; Nagata, T; Yamada, T;
Indirizzi:
Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan Keio Univ Yokohama Kanagawa Japan 2238522 kohama, Kanagawa 2238522, Japan Mitsui Chem Inc, Chem Synth Lab, Sodegaura, Chiba 2990265, Japan Mitsui Chem Inc Sodegaura Chiba Japan 2990265 gaura, Chiba 2990265, Japan
Titolo Testata:
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
, volume: 57, anno: 2001,
parte:, 3
pagine: m124 - m126
SICI:
1600-5368(20010301)57:<m124:('>2.0.ZU;2-X
Fonte:
ISI
Lingua:
ENG
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
11
Recensione:
Indirizzi per estratti:
Indirizzo: Ohba, S Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Hiyoshi 3-14-1, Yokohama, Kanagawa 2238522, Japan Keio Univ Hiyoshi 3-14-1 Yokohama Kanagawa Japan 2238522 22, Japan
Citazione:
S. Ohba et al., "(-)(D)-aquabromo{3,3 '-[(1R,2R)-1,2-bis(2,4,6-trimethyl-phenyl)ethane-1,2-diylbis(nitrilomethylidyne)]bis-(pentane-2,4-dionato)-N,N ',O,O '}cobalt(III) tetrahydrofuran solvate", ACT CRYST E, 57, 2001, pp. m124-m126

Abstract

In the title compound, (-)(D)-[CoBr(C32H38N2O4)(H2O)]C-.-(4) H8O, the benzylic C atoms of the tetradentate ligand have an R,R configuration. There are two independent complex molecules in the asymmetric unit, essentially of the same geometry and absolute configuration. It was possible to determine the absolute configuration based on the Flack parameter, although the crystal structure has a pseudo-center of symmetry.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 23/09/20 alle ore 12:57:59