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Titolo:
Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor-acceptor substituted C-C bond
Autore:
Suzuki, T; Ono, K; Kawai, H; Tsuji, T;
Indirizzi:
Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600810 oro, Hokkaido 0600810, Japan
Titolo Testata:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2
fascicolo: 9, , anno: 2001,
pagine: 1798 - 1801
SICI:
1472-779X(200109):9<1798:LXSAOP>2.0.ZU;2-D
Fonte:
ISI
Lingua:
ENG
Soggetto:
ORBITAL INTERACTIONS; SINGLE BOND; LONG BOND; CHROMOPHORES; LENGTHS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
24
Recensione:
Indirizzi per estratti:
Indirizzo: Suzuki, T Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600810 ido 0600810, Japan
Citazione:
T. Suzuki et al., "Low-temperature X-ray structural analysis of propanedinitrile derivatives substituted with a bis(4-dimethylaminophenyl)methyl group: the origin of elongation of the donor-acceptor substituted C-C bond", J CHEM S P2, (9), 2001, pp. 1798-1801

Abstract

Push-pull type substitution at C-sp 3-C-sp 3 in the title. compounds does not have special electronic effects on the bond length, and the observed expansion can be best accounted for by steric interaction between substituents.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/01/20 alle ore 19:06:28