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Titolo:
The Bilik reaction
Autore:
Petrus, L; Petrusova, M; Hricoviniova, Z;
Indirizzi:
Slovak Acad Sci, Inst Chem, Bratislava 84238, Slovakia Slovak Acad Sci Bratislava Slovakia 84238 em, Bratislava 84238, Slovakia
Titolo Testata:
GLYOSCIENCE: EPIMERISATION, ISOMERISATION AND REARRANGEMENT REACTIONS OF CARBOHYDRATES
, volume: 215, anno: 2001,
pagine: 15 - 41
SICI:
0342-6793(2001)215:<15:TBR>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
ACID-CATALYZED ISOMERIZATION; MOLYBDATE IONS; C-2 EPIMERIZATION; CARBON-SKELETON; NICKEL(II) COMPLEXES; D-HAMAMELOSE; NMR-SPECTRA; CALCIUM-ION; D-FRUCTOSE; D-GLUCOSE;
Keywords:
Bilik reaction; molybdic acid catalysis; epimerization; carbon-skeleton rearrangement; aldoses; 2-ketoses; 2-C-(hydroxymethyl)aldoses; hamamelose; sedoheptulose;
Tipo documento:
Review
Natura:
Collana
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
89
Recensione:
Indirizzi per estratti:
Indirizzo: Petrus, L Slovak Acad Sci, Inst Chem, Dubravska Cesta 9, Bratislava 84238,Slovakia Slovak Acad Sci Dubravska Cesta 9 Bratislava Slovakia 84238 kia
Citazione:
L. Petrus et al., "The Bilik reaction", T CURR CHEM, 215, 2001, pp. 15-41

Abstract

The introduction of the Bilik reaction, the molybdic acid catalyzed interconversion of epimeric aldoses, is an important milestone in carbohydrate chemistry. The essentials of this unique, stereospecific carbon-skeleton rearrangement of epialdoses are presented. Emphasis is laid on the latest developments in the area, namely the mutual interconversion of 2-ketoses and 2-C-(hydroxymethyl)aldoses, a reaction that is exploited for the preparation of some important representatives of these reducing sugars. Mechanistic studies with isotopically substituted D-fructoses are also described.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 19/09/20 alle ore 17:54:29