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Titolo:
Catalytic asymmetric synthesis of 1,1 '-spirobi[indan-3,3 '-dione] via a double intramolecular C-H insertion process
Autore:
Takahashi, T; Tsutsui, H; Tamura, M; Kitagaki, S; Nakajima, M; Hashimoto, S;
Indirizzi:
Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600812 oro, Hokkaido 0600812, Japan
Titolo Testata:
CHEMICAL COMMUNICATIONS
fascicolo: 17, , anno: 2001,
pagine: 1604 - 1605
SICI:
1359-7345(20010907):17<1604:CASO1'>2.0.ZU;2-8
Fonte:
ISI
Lingua:
ENG
Soggetto:
ENANTIOSELECTIVE SYNTHESIS; HIGHLY EFFICIENT; CONSTRUCTION; LIGANDS; HYDROGENATION; ANTIBIOTICS; RESOLUTION; REDUCTION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
31
Recensione:
Indirizzi per estratti:
Indirizzo: Hashimoto, S Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812, Japan Hokkaido Univ Sapporo Hokkaido Japan 0600812 0600812, Japan
Citazione:
T. Takahashi et al., "Catalytic asymmetric synthesis of 1,1 '-spirobi[indan-3,3 '-dione] via a double intramolecular C-H insertion process", CHEM COMMUN, (17), 2001, pp. 1604-1605

Abstract

A highly efficient one-pot construction of optically active 1,1 ' -spirobi[indan-3,3 ' -dione] derivative (up to 80% ee) has been achieved by exploiting the double intramolecular C-H insertion reaction of dimethyl 2,2 ' -methylenebis(alpha -diazo-beta -oxobenzenepropanoate) under the influence of dirhodium (II) tetrakis[N-phthaloyl-(R or S)-tert-leucinate] as a catalyst.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 13/07/20 alle ore 04:38:57