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Titolo:
Synthesis and molecular structures of N,N-dialkyl-4-nitrosoaniline adductsof formally d(6) metalloporphyrins of ruthenium and cobalt
Autore:
Chen, L; Fox, JB; Yi, GB; Khan, MA; Richter-Addo, GB;
Indirizzi:
Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA Univ Oklahoma Norman OK USA 73019 pt Chem & Biochem, Norman, OK 73019 USA
Titolo Testata:
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
fascicolo: 9, volume: 5, anno: 2001,
pagine: 702 - 707
SICI:
1088-4246(200109)5:9<702:SAMSON>2.0.ZU;2-0
Fonte:
ISI
Lingua:
ENG
Soggetto:
SOLID-STATE NMR; ANALOG METALLOPORPHYRINS; OSMIUM PORPHYRINS; COMPLEXES; NITROSYL; OCTAETHYLPORPHYRIN; LIGANDS; TETRAPHENYLPORPHYRIN; METALLOPROTEINS; STEREOCHEMISTRY;
Keywords:
nitrosoarene; X-ray; ruthenium; cobalt; porphyrin; C-nitroso;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
39
Recensione:
Indirizzi per estratti:
Indirizzo: Richter-Addo, GB Univ Oklahoma, Dept Chem & Biochem, 620 Parrington Oval, Norman, OK 73019 USA Univ Oklahoma 620 Parrington Oval Norman OK USA 73019 USA
Citazione:
L. Chen et al., "Synthesis and molecular structures of N,N-dialkyl-4-nitrosoaniline adductsof formally d(6) metalloporphyrins of ruthenium and cobalt", J PORPHYR P, 5(9), 2001, pp. 702-707

Abstract

Para-aminosubstituted nitrosoarenes react with Ru(CO)(OEP) or [Co(TPP)(THF)(2)]SbF6 (OEP2- 2,3,7,8,12,13,17,18-octaethylporphyrinato dianion, TPP2- =5,10,15,20-tetraphenylporphyrinato dianion) to generate Ru(OEP)(ONC6H4NMe2)(2) and [Co(TPP)(ONC6H4NR2)(2)]SbF6 (R =Me, Et), respectively, in fair to high yields. These N-bound nitrosoarene complexes have been characterized by spectroscopic methods. The complexes Ru(OEP)(ONC6H4NMe2)(2) and [Co(TPP)(ONC6H4NMe2)(2)]ClO4 have also been characterized by single-crystal X-ray crystallography. Their structures represent the first reported solid-state structures of Ru and Co porphyrins containing C-nitroso ligands. Copyright (C) 2001 John Wiley & Sons, Ltd.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 10/04/20 alle ore 16:07:16