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Titolo:
Enantioselective synthesis of cis-1,2-dialkyl substituted cyclopentanoid and isoprostane building blocks via 6-exo-trigonal radical cyclizations
Autore:
Zanoni, G; Re, S; Meriggi, A; Castronovo, F; Vidari, G;
Indirizzi:
Univ Pavia, Dipartimento Chim Organ, I-27100 Pavia, Italy Univ Pavia Pavia Italy I-27100 rtimento Chim Organ, I-27100 Pavia, Italy
Titolo Testata:
TETRAHEDRON-ASYMMETRY
fascicolo: 12, volume: 12, anno: 2001,
pagine: 1785 - 1792
SICI:
0957-4166(20010716)12:12<1785:ESOCSC>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
ASYMMETRIC-SYNTHESIS; COREY LACTONE; 12-EPI-PGF(2-ALPHA); PROSTAGLANDINS; MECHANISM; CIS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
29
Recensione:
Indirizzi per estratti:
Indirizzo: Vidari, G Univ Pavia, Dipartimento Chim Organ, Viale Taramelli 10, I-27100Pavia, Italy Univ Pavia Viale Taramelli 10 Pavia Italy I-27100 Pavia, Italy
Citazione:
G. Zanoni et al., "Enantioselective synthesis of cis-1,2-dialkyl substituted cyclopentanoid and isoprostane building blocks via 6-exo-trigonal radical cyclizations", TETRAHEDR-A, 12(12), 2001, pp. 1785-1792

Abstract

Two different 6-exo-trigonal cyclizations of enantiomerically enriched 6-heptenyl radicals readily afforded versatile synthetic precursors of cis-1,2-dialkyl substituted cyclopentane derivatives. Starting from one of these intermediates, we accomplished an enantiospecific formal synthesis of two important isoprostanes, namely 15-F-2c-IsoP and ent-15-F-2c-IsoP. (C) 2001 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/04/20 alle ore 11:03:18