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Titolo:
Selective reduction of aldehydes via BINOL-Zr complex
Autore:
Lorca, M; Kuhn, D; Kurosu, M;
Indirizzi:
Florida State Univ, Dept Chem, Tallahassee, FL 32306 USA Florida State Univ Tallahassee FL USA 32306 em, Tallahassee, FL 32306 USA
Titolo Testata:
TETRAHEDRON LETTERS
fascicolo: 36, volume: 42, anno: 2001,
pagine: 6243 - 6246
SICI:
0040-4039(20010903)42:36<6243:SROAVB>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
BETA-HYDROXY KETONES; CARBONYL-COMPOUNDS; ZIRCONIUM;
Keywords:
selective reduction; BINOL; zirconium complex;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
20
Recensione:
Indirizzi per estratti:
Indirizzo: Kurosu, M Florida State Univ, Dept Chem, Tallahassee, FL 32306 USA FloridaState Univ Tallahassee FL USA 32306 assee, FL 32306 USA
Citazione:
M. Lorca et al., "Selective reduction of aldehydes via BINOL-Zr complex", TETRAHEDR L, 42(36), 2001, pp. 6243-6246

Abstract

An easily assembled catalyst from (+/-)-BINOL (1,1 ' -bi-naphthol) and Zr(O ' Pr)(4). ' PrOH selectively reduces aldehydes at room temperature. Ketones remain intact under these conditions. A catalytic amount of BINOL-Zr complex in the presence of 2-propanol also effectively reduces a variety of chiral and achiral aldehydes. (C) 2001 Published by Elsevier Science Ltd.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 02/12/20 alle ore 07:58:15