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Titolo:
One-step transformation of tricyclopentabenzene (trindane, C15H18) to bicyclo(10.3.0)pentadec-1(12)ene-2,6,7,11-tetrone (C15H18O4) and its aldol product, 12-hydroxy-16-oxatetracyclo-(10.3.1.0.O-1,5(7,11))hexadec-7(11)ene-2,6-dione (C15H18O4)
Autore:
Ranganathan, S; Muraleedharan, KM; Rao, CC; Vairamani, M; Karle, IL;
Indirizzi:
Indian Inst Chem Technol, Discovery Lab, Hyderabad 500007, Andhra Pradesh,India Indian Inst Chem Technol Hyderabad Andhra Pradesh India 500007 desh,India Jawaharlal Nehru Ctr Adv Sci Res, Bangalore 560067, Karnataka, India Jawaharlal Nehru Ctr Adv Sci Res Bangalore Karnataka India 560067 , India Indian Inst Chem Technol, Mass Spect Lab, Hyderabad 500007, Andhra Pradesh, India Indian Inst Chem Technol Hyderabad Andhra Pradesh India 500007 esh, India USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA USN Washington DC USA 20375 , Struct Matter Lab, Washington, DC 20375 USA
Titolo Testata:
ORGANIC LETTERS
fascicolo: 16, volume: 3, anno: 2001,
pagine: 2447 - 2449
SICI:
1523-7060(20010809)3:16<2447:OTOT(C>2.0.ZU;2-#
Fonte:
ISI
Lingua:
ENG
Soggetto:
BROWN ALGA; DITERPENOIDS; SKELETON;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
32
Recensione:
Indirizzi per estratti:
Indirizzo: Ranganathan, S Indian Inst Chem Technol, Discovery Lab, Hyderabad 500007, Andhra Pradesh,India Indian Inst Chem Technol Hyderabad Andhra Pradesh India 500007
Citazione:
S. Ranganathan et al., "One-step transformation of tricyclopentabenzene (trindane, C15H18) to bicyclo(10.3.0)pentadec-1(12)ene-2,6,7,11-tetrone (C15H18O4) and its aldol product, 12-hydroxy-16-oxatetracyclo-(10.3.1.0.O-1,5(7,11))hexadec-7(11)ene-2,6-dione (C15H18O4)", ORG LETT, 3(16), 2001, pp. 2447-2449

Abstract

[GRAPHICS]Ozonolysis of I largely results in 2 and 3, having features similar to several classes of natural products. The retention of the C-15 pericycle suggests preference for the cleavage of pi -bonds endo to the cyclopentane ring. This unique property of trindane offers opportunities for synthesis of complex natural products from this hydrocarbon that can be made in quantity byacid-catalyzed trimerizatiion of cyclopentanone.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/09/20 alle ore 16:32:40