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Titolo:
Bionic catalyst design: A photochemical approach to artificial enzyme function
Autore:
Knor, G;
Indirizzi:
Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany Univ Regensburg Regensburg Germany D-93040 , D-93040 Regensburg, Germany
Titolo Testata:
CHEMBIOCHEM
fascicolo: 7-8, volume: 2, anno: 2001,
pagine: 593 -
SICI:
1439-4227(20010803)2:7-8<593:BCDAPA>2.0.ZU;2-J
Fonte:
ISI
Lingua:
ENG
Soggetto:
GALACTOSE-OXIDASE; RADICAL REACTIONS; OXIDATION; ALCOHOLS; ACTIVATION; OXYGEN;
Keywords:
bioinorganic chemistry; enzyme models; homogeneous catalysis; hydrogen transfer; photochemistry;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Citazioni:
25
Recensione:
Indirizzi per estratti:
Indirizzo: Knor, G Univ Regensburg, Inst Anorgan Chem, Univ Str 31, D-93040 Regensburg, Germany Univ Regensburg Univ Str 31 Regensburg Germany D-93040 g, Germany
Citazione:
G. Knor, "Bionic catalyst design: A photochemical approach to artificial enzyme function", CHEMBIOCHEM, 2(7-8), 2001, pp. 593

Abstract

To mimic the regulation mechanisms and the selective chemistry of enzymes in the absence of a protein environment, a novel bio-inspired catalyst design strategy is applied with photosensitive coordination compounds acting asphotocatalytic artificial enzymes (photozymes). As an example, a robust synthetic oxidoreductase photozyme is described (see reaction scheme; M = Sb)and its efficiency is compared to that of native enzymes and other functional model compounds.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/03/20 alle ore 14:42:32