Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
Asymmetric synthesis of the new marine epoxy lipid, (6S,7S,9S,10S)-6,9-epoxynonadec-18-ene-7,10-diol
Autore:
Yoda, H; Maruyama, K; Takabe, K;
Indirizzi:
Univ Shizouka, Fac Engn, Dept Mol Sci, Hamamatsu, Shizuoka 4328561, Japan Univ Shizouka Hamamatsu Shizuoka Japan 4328561 u, Shizuoka 4328561, Japan
Titolo Testata:
TETRAHEDRON-ASYMMETRY
fascicolo: 10, volume: 12, anno: 2001,
pagine: 1403 - 1406
SICI:
0957-4166(20010622)12:10<1403:ASOTNM>2.0.ZU;2-2
Fonte:
ISI
Lingua:
ENG
Soggetto:
ALGA NOTHEIA-ANOMALA; BROWN ALGA; STEREOSELECTIVE SYNTHESIS; NATURAL PRODUCT; SUBSTITUTED TETRAHYDROFURANS; ALPHA-HYDROXYPYRROLIDINE; (6S,7S,9R,10R)-6,9-EPOXYNONADEC-18-ENE-7,10-DIOL; ROUTE; TETRAHYDROPYRAN; BISEPOXIDES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
37
Recensione:
Indirizzi per estratti:
Indirizzo: Yoda, H Univ Shizouka, Fac Engn, Dept Mol Sci, Hamamatsu, Shizuoka 4328561, Japan Univ Shizouka Hamamatsu Shizuoka Japan 4328561 oka 4328561, Japan
Citazione:
H. Yoda et al., "Asymmetric synthesis of the new marine epoxy lipid, (6S,7S,9S,10S)-6,9-epoxynonadec-18-ene-7,10-diol", TETRAHEDR-A, 12(10), 2001, pp. 1403-1406

Abstract

An efficient and stereocontrolled process is described for the preparationof (6S, 7S, 9S, 10S)-6,9-epoxynonadee-18-ene-7.10-diol, a marine epoxy lipid isolated from the brown alga, Notheia anomala. The key 2,3,5-trisubstituted tetrahydrofuran ring was constructed by stereoselective hydrogenation of the hemiketal derivative elaborated through nucleophilic addition of Grignard reagent in the presence of CeCl3 to the highly functionalized lactone derived from L-galactono-1,4-lactone,4-lactone. (C) 2001 Elsevier Science Ltd. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 26/09/20 alle ore 10:52:25