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Titolo:
Induction of diastereoselectivity in Fe(II) tris(amino acid-bipyridine) complexes
Autore:
Ahn, DR; Kim, TW; Hong, JI;
Indirizzi:
Seoul Natl Univ, Coll Nat Sci, Sch Chem & Mol Engn, Seoul 151747, South Korea Seoul Natl Univ Seoul South Korea 151747 Engn, Seoul 151747, South Korea
Titolo Testata:
JOURNAL OF ORGANIC CHEMISTRY
fascicolo: 15, volume: 66, anno: 2001,
pagine: 5008 - 5011
SICI:
0022-3263(20010727)66:15<5008:IODIFT>2.0.ZU;2-M
Fonte:
ISI
Lingua:
ENG
Soggetto:
METAL-COMPLEXES; STEREOSELECTIVE SYNTHESIS; MOLECULES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
21
Recensione:
Indirizzi per estratti:
Indirizzo: Hong, JI Seoul Natl Univ, Coll Nat Sci, Sch Chem & Mol Engn, Seoul 151747,South Korea Seoul Natl Univ Seoul South Korea 151747 ul 151747, South Korea
Citazione:
D.R. Ahn et al., "Induction of diastereoselectivity in Fe(II) tris(amino acid-bipyridine) complexes", J ORG CHEM, 66(15), 2001, pp. 5008-5011

Abstract

A group of iron(II) tris-bipyridine complexes bearing L-amino acids (L-Lys, L-Phe, L-Ser, L-Val) was prepared to investigate the predetermination of chirality of metal complexes by the chiral amino acid subunits. Noncovalentinteractions and solvent polarity seemed to be important factors in inducing diastereoselectivity of the metal complexes. These phenomena were explained by H-1 NMR and CD spectroscopic studies and molecular mechanics calculations.

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Documento generato il 27/11/20 alle ore 07:32:05