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Titolo:
Layered LixMn1-yCoyO2 intercalation electrodes-influence of ion exchange on capacity and structure upon cycling
Autore:
Robertson, AD; Armstrong, AR; Bruce, PG;
Indirizzi:
Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland Univ St Andrews St Andrews Fife Scotland KY16 9ST Y16 9ST, Fife, Scotland
Titolo Testata:
CHEMISTRY OF MATERIALS
fascicolo: 7, volume: 13, anno: 2001,
pagine: 2380 - 2386
SICI:
0897-4756(200107)13:7<2380:LLIEOI>2.0.ZU;2-6
Fonte:
ISI
Lingua:
ENG
Soggetto:
RECHARGEABLE LITHIUM BATTERIES; POSITIVE ELECTRODE; CATHODE MATERIALS; LIMNO2; LI; SPINEL; OXIDE; LI(MN1-YCOY)O-2; CHEMISTRY; INSERTION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Engineering, Computing & Technology
Citazioni:
29
Recensione:
Indirizzi per estratti:
Indirizzo: Bruce, PG Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland Univ St Andrews St Andrews Fife Scotland KY16 9ST ife, Scotland
Citazione:
A.D. Robertson et al., "Layered LixMn1-yCoyO2 intercalation electrodes-influence of ion exchange on capacity and structure upon cycling", CHEM MATER, 13(7), 2001, pp. 2380-2386

Abstract

Layered LixMn1-yCoyO2 with the O3 (alpha NaFeO2) structure has been prepared from the analogous P3 sodium phase by ion exchange using LiBr in either ethanol at 80 degreesC or hexanol at 160 degreesC. The former preserves, tosome extent, vacancies present on the transitional metal sites of the sodium phase, whereas the latter eliminates the vacancies. Materials with vacancies exhibit better performance as cathodes in rechargeable lithium batteries. The 2.5% Co doped material prepared in ethanol exhibits capacities of 200 mAhg(-1) when cycled at C/8 between 2.4 and 4.6 V at 30 degreesC and with a fade of only 0.08% per cycle. A capacity of 180 mA h g(-1) can be obtained at C/2 and 200 mAhg(-1) at C rate and 55 degreesC. Importantly, this performance is obtained despite the fact that the materials convert to spinel-like phases on cycling. The spinel-like phases that form are nanostructured, with each crystallite being composed of a mosaic of nanodomains. The relief of strain at the domain wall boundaries accompanying the cubic-tetragonal phase transition may explain, at least in part, the facile cycling of these materials over a wide composition range (including the 3 V plateau) compared with high-temperature spinel which does not possess such nanodomains. Furthermore, vacancies present in the ethanol materials appear to migrate to the domain walls on cycling, rendering even more facile the Jahn-Teller-driven phase transformation on cycling these materials compared with those prepared in hexanol.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/09/20 alle ore 15:39:31