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Titolo:
Exchange of short-chain oxygenated volatile organic compounds (VOCs) between plants and the atmosphere: A compilation of field and laboratory studies
Autore:
Kesselmeier, J;
Indirizzi:
Max Planck Inst Chem, Abt Biogeochem, D-55020 Mainz, Germany Max Planck Inst Chem Mainz Germany D-55020 ochem, D-55020 Mainz, Germany
Titolo Testata:
JOURNAL OF ATMOSPHERIC CHEMISTRY
fascicolo: 3, volume: 39, anno: 2001,
pagine: 219 - 233
SICI:
0167-7764(2001)39:3<219:EOSOVO>2.0.ZU;2-Q
Fonte:
ISI
Lingua:
ENG
Soggetto:
QUERCUS-ILEX L.; REACTION MASS-SPECTROMETRY; ACETIC-ACIDS; FORMIC-ACID; BIOGENIC EMISSIONS; ACETALDEHYDE; TROPOSPHERE; ISOPRENE; LEAVES; MONOTERPENES;
Keywords:
volatile organic compounds; biogenic emission; biogenic deposition; compensation point; organic acids; formic acid; acetic acid; carbonyls; acetaldehyde; formaldehyde;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Agriculture,Biology & Environmental Sciences
Physical, Chemical & Earth Sciences
Citazioni:
50
Recensione:
Indirizzi per estratti:
Indirizzo: Kesselmeier, J Max Planck Inst Chem, Abt Biogeochem, Postfach 3060, D-55020 Mainz, Germany Max Planck Inst Chem Postfach 3060 Mainz Germany D-55020 y
Citazione:
J. Kesselmeier, "Exchange of short-chain oxygenated volatile organic compounds (VOCs) between plants and the atmosphere: A compilation of field and laboratory studies", J ATMOS CH, 39(3), 2001, pp. 219-233

Abstract

Field and laboratory investigations of the exchange of the short-chain organic acids - formic acid and acetic acid - as well as their homologous aldehydes are discussed. Both acids are substantially released from several plant species. Emission measurements under field conditions are compiled to give an overview of three years of measurements. Emission rates from several tree species were found in the range between zero and 60 nmoles m(-2) min(-1) for acetic acid and between zero and 90 nmoles m(-2) min(-1) for formic acid though also a deposition has been observed to orange trees. Investigations under laboratory conditions showed an order of magnitude lower emission rates with significant differences under light and dark conditions, and adeposition was observed under certain conditions. Hence, low emission rates or even a bi-directional exchange, emission as well as deposition have tobe taken into account. Further differences between field and laboratory studies are discussed considering age of trees, stress effects and a potential production of acids by photochemical conversion of precursors inside enclosures during sampling. Field data on the exchange of form- and acetaldehyde show a complex behavior. We found emission as well as uptake. The bi-directional exchange is significantly triggered by the ambient mixing ratios ofboth aldehyde species and exhibits a compensation point. Further studies are needed for generalization of the exchange of these and potentially also for other compounds.

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Documento generato il 19/09/20 alle ore 21:34:51