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Titolo:
Hydrolysis of an isolable selenoseleninate under acidic and alkaline conditions
Autore:
Ishii, A; Takahashi, T; Nakayama, J;
Indirizzi:
Saitama Univ, Fac Sci, Dept Chem, Urawa, Saitama 3388570, Japan Saitama Univ Urawa Saitama Japan 3388570 m, Urawa, Saitama 3388570, Japan
Titolo Testata:
HETEROATOM CHEMISTRY
fascicolo: 4, volume: 12, anno: 2001,
pagine: 198 - 203
SICI:
1042-7163(2001)12:4<198:HOAISU>2.0.ZU;2-N
Fonte:
ISI
Lingua:
ENG
Soggetto:
SELENENIC ACIDS; ORGANOSELENIUM CHEMISTRY; SYN ELIMINATION; MECHANISM; ANHYDRIDES; SELENOXIDES; REACTIVITY; THIOLS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
27
Recensione:
Indirizzi per estratti:
Indirizzo: Ishii, A Saitama Univ, Fac Sci, Dept Chem, Urawa, Saitama 3388570, Japan Saitama Univ Urawa Saitama Japan 3388570 Saitama 3388570, Japan
Citazione:
A. Ishii et al., "Hydrolysis of an isolable selenoseleninate under acidic and alkaline conditions", HETEROAT CH, 12(4), 2001, pp. 198-203

Abstract

Acid-catalyzed hydrolysis of a seleno-seleninate [TripSe(O)SeTrip](Trip = 9-triptycyl) in 2 M HClO4-1,4-dioxane at room temperature yielded the selenenic acid (TripSeOH). Alkaline hydrolysis of TripSe(O)SeTrip gave the diselenide (TripSeSeTrip) and the seleninic acid (TripSeO(2)H), where air oxidations of the resulting selenol (TripSeH) and TripSeOH occur at a considerable rate. (C) 2001 John Wiley & Sons, Inc.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 11/07/20 alle ore 07:30:08