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Titolo:
Peculiar physical properties of (ET)(3)(MnCl4)(TCE)
Autore:
Naito, T; Inabe, T; Takeda, K; Awaga, K; Akutagawa, T; Hasegawa, T; Nakamura, T; Kakiuchi, T; Sawa, H; Yamamoto, T; Tajima, H;
Indirizzi:
Hokkaido Univ, Div Chem, Sapporo, Hokkaido 060, Japan Hokkaido Univ Sapporo Hokkaido Japan 060 em, Sapporo, Hokkaido 060, Japan Univ Tokyo, Dept Basic Sci, Tokyo, Japan Univ Tokyo Tokyo JapanUniv Tokyo, Dept Basic Sci, Tokyo, Japan Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 060, Japan Hokkaido Univ Sapporo Hokkaido Japan 060 ci, Sapporo, Hokkaido 060, Japan Chiba Univ, Dept Phys, Chiba 260, Japan Chiba Univ Chiba Japan 260Chiba Univ, Dept Phys, Chiba 260, Japan Univ Tokyo, Inst Solid State Phys, Tokyo, Japan Univ Tokyo Tokyo JapanUniv Tokyo, Inst Solid State Phys, Tokyo, Japan
Titolo Testata:
SYNTHETIC METALS
fascicolo: 1-3, volume: 120, anno: 2001,
pagine: 877 - 878
SICI:
0379-6779(20010315)120:1-3<877:PPPO(>2.0.ZU;2-0
Fonte:
ISI
Lingua:
ENG
Soggetto:
MAGNETIC ANIONS; SALTS; CONDUCTORS; CRYSTAL;
Keywords:
organic conductors based on radical cation and/or anion salts;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
9
Recensione:
Indirizzi per estratti:
Indirizzo: Naito, T Hokkaido Univ, Div Chem, Sapporo, Hokkaido 060, Japan Hokkaido Univ Sapporo Hokkaido Japan 060 ro, Hokkaido 060, Japan
Citazione:
T. Naito et al., "Peculiar physical properties of (ET)(3)(MnCl4)(TCE)", SYNTH METAL, 120(1-3), 2001, pp. 877-878

Abstract

The title compound (ET=bis(ethylene)dithiotetrathiafulvalene TCE=1,1,2-trichloroethane) is a new molecular conductor obtained by the standard electrochemical oxidation. It has a beta " -donor arrangement without any crystallographic disorder or non-integral stoichiometry. The electrical behavior, which was sensitive to pressure, was semiconducting (35 Scm(-1) at RT) at ambient pressure with a clear hump around 60 K accompanied by a large hysterisis. No corresponding anomalies, however, were observed in its temperature-dependent magnetic susceptibility. The calculated band structure is two-dimensional, which agrees well with the observed physical properties.

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Documento generato il 22/09/20 alle ore 23:22:52