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Titolo:
Model systems for flavoenzyme activity. Control of flavin recognition via specific electrostatic interactions
Autore:
Goodman, AJ; Breinlinger, EC; McIntosh, CM; Grimaldi, LN; Rotello, VM;
Indirizzi:
Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA Univ Massachusetts Amherst MA USA 01003 Dept Chem, Amherst, MA 01003 USA
Titolo Testata:
ORGANIC LETTERS
fascicolo: 10, volume: 3, anno: 2001,
pagine: 1531 - 1534
SICI:
1523-7060(20010517)3:10<1531:MSFFAC>2.0.ZU;2-1
Fonte:
ISI
Lingua:
ENG
Soggetto:
DESULFOVIBRIO-VULGARIS HILDENBOROUGH; SITE-DIRECTED MUTAGENESIS; MOLECULAR RECOGNITION; STACKING INTERACTIONS; PI INTERACTION; AROMATIC INTERACTIONS; REDOX POTENTIALS; HYDROGEN-BOND; FLAVODOXIN; MODULATION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
30
Recensione:
Indirizzi per estratti:
Indirizzo: Rotello, VM Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA Univ Massachusetts Amherst MA USA 01003 Amherst, MA 01003 USA
Citazione:
A.J. Goodman et al., "Model systems for flavoenzyme activity. Control of flavin recognition via specific electrostatic interactions", ORG LETT, 3(10), 2001, pp. 1531-1534

Abstract

A model system has been used to study the interactions of dipole containing aromatic systems with oxidized and reduced flavin, Ab initio computational and experimental studies show that dipole orientation within the host is a critical determinant for recognition and redox behavior of the flavin guest.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 06/04/20 alle ore 08:30:41