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Titolo:
N '-tert-butyl-N '-aroyl-N-(alkoxycarbonylmethyl)-N-aroylhydrazines, a novel nonsteroidal ecdysone agonist: syntheses, insecticidal activity, conformational, and crystal structure analysis
Autore:
Cao, S; Qian, X; Song, G;
Indirizzi:
E China Univ Sci & Technol, Inst Pesticides & Pharmaceut, Shanghai 200237,Peoples R China E China Univ Sci & Technol Shanghai Peoples R China 200237 oples R China
Titolo Testata:
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
fascicolo: 3, volume: 79, anno: 2001,
pagine: 272 - 278
SICI:
0008-4042(200103)79:3<272:N''AN>2.0.ZU;2-4
Fonte:
ISI
Lingua:
ENG
Soggetto:
BUDWORM CHORISTONEURA-FUMIFERANA; ANALOGS;
Keywords:
N '-tert-butyl-N '-aroyl; N-(alkoxycarbonylmethyl); N-aroylhydrazine; syntheses; insecticidal activity; conformation; crystal structure;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
11
Recensione:
Indirizzi per estratti:
Indirizzo: Qian, X Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China Dalian Univ Technol Dalian Peoples R China 116012 eoples R China
Citazione:
S. Cao et al., "N '-tert-butyl-N '-aroyl-N-(alkoxycarbonylmethyl)-N-aroylhydrazines, a novel nonsteroidal ecdysone agonist: syntheses, insecticidal activity, conformational, and crystal structure analysis", CAN J CHEM, 79(3), 2001, pp. 272-278

Abstract

Seventeen N'-tert-butyl-N'-aroyl-N-(alkoxycarbonylmethyl)-N-aroylhydrazines were synthesized, and their insecticidal activities against armyworm (Leucania separata (Walker)) were tested. The conformation and structure of compound 1b was studied by H-1 NMR spectroscopy and X-ray crystallography. Thecrystal structure belongs to the orthorhombic system and the N-N bond adopts a gauche conformation, which was assumed to be the active conformation, with a dihedral angle of 69.9 degrees.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 05/07/20 alle ore 13:37:38