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Titolo:
On the crystal engineering of organogallium alkoxides derived from primary-amine alcohols - Relationships between hydrogen bonding and donor-acceptorbonds
Autore:
Lewinski, J; Zachara, J; Kopec, T; Starowieyski, KB; Lipkowski, J; Justyniak, I; Kolodziejczyk, E;
Indirizzi:
Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland Warsaw Univ Technol Warsaw Poland PL-00664 Chem, PL-00664 Warsaw, Poland Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland Polish Acad Sci Warsaw Poland PL-01224 hys Chem, PL-01224 Warsaw, Poland
Titolo Testata:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
fascicolo: 5, , anno: 2001,
pagine: 1123 - 1126
SICI:
1434-1948(200105):5<1123:OTCEOO>2.0.ZU;2-J
Fonte:
ISI
Lingua:
ENG
Soggetto:
SOLID-STATE; COMPLEXES; DIMETHYLALUMINUM; PYRAZOLYL; LIGAND;
Keywords:
gallium; alkoxides; crystal engineering; donor-acceptor systems; hydrogen bonds;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
26
Recensione:
Indirizzi per estratti:
Indirizzo: Lewinski, J Warsaw Univ Technol, Dept Chem, Noakowskiego 3, PL-00664 Warsaw, Poland Warsaw Univ Technol Noakowskiego 3 Warsaw Poland PL-00664 and
Citazione:
J. Lewinski et al., "On the crystal engineering of organogallium alkoxides derived from primary-amine alcohols - Relationships between hydrogen bonding and donor-acceptorbonds", EUR J INORG, (5), 2001, pp. 1123-1126

Abstract

The crystal structure analysis of model organogallium aminealkoxides Me2Ga(OCH2CH2CH2NH2) (2) and (Me2Ga(mu -OCH2CH(CH3)NH2))(2) (3), demonstrate howhydrogen bonding can effectively compete with metal-ligand coordination preferences in determining the molecular and crystal structure and how conformational changes in a ligand and increased steric bulk on the carbon atom adjacent to the amine group can impart on a network morphology and molecularaggregations.

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Documento generato il 21/09/20 alle ore 15:55:55