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Titolo:
A facile synthesis of a (+/-)-2,3-disubstituted maleic anhydride segment of tautomycin
Autore:
Deshpande, AM; Natu, AA; Argade, NP;
Indirizzi:
Natl Chem Lab, Div Organ Chem Synth, Poona 411008, Maharashtra, India NatlChem Lab Poona Maharashtra India 411008 a 411008, Maharashtra, India
Titolo Testata:
SYNTHESIS-STUTTGART
fascicolo: 5, , anno: 2001,
pagine: 702 - 704
SICI:
0039-7881(200104):5<702:AFSOA(>2.0.ZU;2-A
Fonte:
ISI
Lingua:
ENG
Soggetto:
PROTEIN PHOSPHATASE INHIBITOR; (BROMOMETHYL)METHYLMALEIC ANHYDRIDE; ACID;
Keywords:
tautomycin; antifungal antibiotic; regioselective NBS-bromination; part structure synthesis;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Life Sciences
Physical, Chemical & Earth Sciences
Citazioni:
14
Recensione:
Indirizzi per estratti:
Indirizzo: Argade, NP Natl Chem Lab, Div Organ Chem Synth, Poona 411008, Maharashtra,India Natl Chem Lab Poona Maharashtra India 411008 aharashtra, India
Citazione:
A.M. Deshpande et al., "A facile synthesis of a (+/-)-2,3-disubstituted maleic anhydride segment of tautomycin", SYNTHESIS-S, (5), 2001, pp. 702-704

Abstract

A convenient method for construction of a (+/-)-2,3-disubstituted maleic anhydride segment of antibiotic tautomycin is reported. The key steps involved in the synthesis are chemoselective condensation of diethyl malonate with 2-(bromomethyl)-3-methylmaleic anhydride (3) and regioselective NBS-bromination of the maleic anhydride derivative 7.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 09/07/20 alle ore 13:57:12