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Titolo:
The 'one-pot' syntheses of alpha,alpha '-diphosphino-substituted imines: aunique reaction of bulky bis(dialkylamino)chlorophosphines
Autore:
Baceiredo, A; Bertrand, G; Dyer, PW; Fawcett, J; Griep-Raming, N; Guerret, O; Hanton, MJ; Russell, DR; Williamson, AM;
Indirizzi:
Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England Univ Leicester Leicester Leics England LE1 7RH er LE1 7RH, Leics, England Univ Toulouse 3, Lab Heterochim Fondamentale & Appliquee, ESA 5069, F-31062 Toulouse, France Univ Toulouse 3 Toulouse France F-31062 A 5069, F-31062 Toulouse, France Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England Univ London Imperial Coll Sci Technol & Med London England SW7 2AY gland
Titolo Testata:
NEW JOURNAL OF CHEMISTRY
fascicolo: 4, volume: 25, anno: 2001,
pagine: 591 - 596
SICI:
1144-0546(200104)25:4<591:T'SOA'>2.0.ZU;2-3
Fonte:
ISI
Lingua:
ENG
Soggetto:
SINGLE ELECTRON-TRANSFER; N-PYRROLYL PHOSPHINES; PI-ACCEPTOR CHARACTER; LITHIUM DIISOPROPYLAMIDE; COORDINATION CHEMISTRY; TRIVALENT PHOSPHORUS; ASYMMETRIC CATALYSIS; METAL-COMPLEXES; LIGANDS; BOND;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
46
Recensione:
Indirizzi per estratti:
Indirizzo: Dyer, PW Univ Leicester, Dept Chem, Univ Rd, Leicester LE1 7RH, Leics, England Univ Leicester Univ Rd Leicester Leics England LE1 7RH s, England
Citazione:
A. Baceiredo et al., "The 'one-pot' syntheses of alpha,alpha '-diphosphino-substituted imines: aunique reaction of bulky bis(dialkylamino)chlorophosphines", NEW J CHEM, 25(4), 2001, pp. 591-596

Abstract

The reaction between various bis(dialkylamino)chlorophosphines and N-isopropyl-substituted lithium amides afforded bis(alpha,alpha'-phosphino)imines in a 'one-pot' procedure. These compounds react with sulfur to generate intramolecularly hydrogen-bonded ylide derivatives. The molecular structure of((Pr2N)-N-i)(2)PCH2C(=NBut)CH2P(NPri)(2) has been determined by X-ray crystallography.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 08/04/20 alle ore 09:08:03