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Titolo:
Mechanism of alkene aziridination in the [(biaryldiimine)Cu-I] catalyst system; precise substrate orientation via two-centre binding
Autore:
Gillespie, KM; Crust, EJ; Deeth, RJ; Scott, P;
Indirizzi:
Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England Univ Warwick Coventry W Midlands England CV4 7AL 7AL, W Midlands, England
Titolo Testata:
CHEMICAL COMMUNICATIONS
fascicolo: 8, , anno: 2001,
pagine: 785 - 786
SICI:
1359-7345(2001):8<785:MOAAIT>2.0.ZU;2-R
Fonte:
ISI
Lingua:
ENG
Soggetto:
ENANTIOSELECTIVE CYCLOPROPANATION; OLEFINS; LIGANDS; BIS(OXAZOLINE); COMPLEXES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
20
Recensione:
Indirizzi per estratti:
Indirizzo: Deeth, RJ Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England Univ Warwick Coventry W Midlands England CV4 7AL lands, England
Citazione:
K.M. Gillespie et al., "Mechanism of alkene aziridination in the [(biaryldiimine)Cu-I] catalyst system; precise substrate orientation via two-centre binding", CHEM COMMUN, (8), 2001, pp. 785-786

Abstract

The highly enantioselective (less than or equal to 98%) aziridination of cinnamate esters is achieved using the title catalyst system via a concertednon-polar mechanism involving ancillary binding of carbonyl group to copper.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 12/07/20 alle ore 08:50:30