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Titolo:
Inclusion polymerization low-dimensional and space-dependent polymerization
Autore:
Miyata, M; Sada, K;
Indirizzi:
Osaka Univ, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan Osaka Univ Suita Osaka Japan 5650871 ife Sci, Suita, Osaka 5650871, Japan
Titolo Testata:
SOFT CHEMISTRY LEADING TO NOVEL MATERIALS
, volume: 191, anno: 2001,
pagine: 99 - 123
SICI:
1012-0386(2001)191:<99:IPLASP>2.0.ZU;2-#
Fonte:
ISI
Lingua:
ENG
Soggetto:
ELECTRON-SPIN-RESONANCE; APOCHOLIC ACID CANALS; METHYL-SUBSTITUTED 1,4-TRANS-POLYBUTADIENES; SOLID-STATE POLYMERIZATION; GAMMA-RAY IRRADIATION; CYCLIC DIENE MONOMERS; C-13 NMR-SPECTRA; DEOXYCHOLIC-ACID; FUNCTIONAL MONOMERS; CHOLIC-ACID;
Keywords:
asymmetric polymerization; channels; chirality; composites; host-guest; inclusion compounds; inclusion polymerization; layers; molecular information; molecular-level space; monomers; nanotechnology; non-covalent process; one-dimensionality; propagating radicals; space effects; stereoregularity; two-dimensionality;
Tipo documento:
Article
Natura:
Collana
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Engineering, Computing & Technology
Citazioni:
135
Recensione:
Indirizzi per estratti:
Indirizzo: Miyata, M Osaka Univ, Dept Mat & Life Sci, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan Osaka Univ 2-1 Yamadaoka Suita Osaka Japan 5650871 650871, Japan
Citazione:
M. Miyata e K. Sada, "Inclusion polymerization low-dimensional and space-dependent polymerization", DEFECT DIFF, 191, 2001, pp. 99-123

Abstract

Inclusion compounds have molecular-level spaces where monomers as guest components form low-dimensional and anisotropic assemblies. The polymerization consists of a cyclic process and proceeds via radical mechanism in most of the cases. Features of the polymerization are understood on the basis of low-dimensionality and space-dependence. Relative sizes between the monomers and the spaces play a decisive role in determining motions of propagatingradicals, polymerizabilities and stereoregularities. The representative one- or two-dimensional polymerization are summarized. After the polymerization low-dimensional molecular composite materials are obtained. In the case of steroidal hosts, the polymerization can be controlled on the basis of chiral and sequential carbon-chains, leading to the idea that inclusion polymerization constitutes a process of molecular information and their expression, like biopolymers such as proteins.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/12/20 alle ore 12:48:13