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Titolo:
Enantioselective synthesis of beta-hydroxy acid derivatives via a one-pot aldol reaction-dynamic kinetic resolution
Autore:
Huerta, FF; Backvall, JE;
Indirizzi:
Univ Stockholm, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, SwedenUniv Stockholm Stockholm Sweden SE-10691 hem, SE-10691 Stockholm, Sweden
Titolo Testata:
ORGANIC LETTERS
fascicolo: 8, volume: 3, anno: 2001,
pagine: 1209 - 1212
SICI:
1523-7060(20010419)3:8<1209:ESOBAD>2.0.ZU;2-W
Fonte:
ISI
Lingua:
ENG
Soggetto:
RUTHENIUM-CATALYZED RACEMIZATION; ENZYMATIC RESOLUTION; ASYMMETRIC-SYNTHESIS; SECONDARY ALCOHOLS; ORGANIC-SYNTHESIS; COMPLEXES; ALDEHYDES; ESTERS; ADDITIONS; ACETATES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
43
Recensione:
Indirizzi per estratti:
Indirizzo: Backvall, JE Univ Stockholm, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden Univ Stockholm Stockholm Sweden SE-10691 Stockholm, Sweden
Citazione:
F.F. Huerta e J.E. Backvall, "Enantioselective synthesis of beta-hydroxy acid derivatives via a one-pot aldol reaction-dynamic kinetic resolution", ORG LETT, 3(8), 2001, pp. 1209-1212

Abstract

Combining dynamic kinetic resolution with an aldol reaction provides access to P-hydroxy ester derivatives with high enantiomeric purity (up to 99% ee) in a one-pot procedure, Only simple starting materials are required in this enantioselective process, and preformation of a silyl enol ether is notnecessary.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 11/07/20 alle ore 16:40:10