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Titolo:
Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes
Autore:
Li, XL; Yang, J; Kozlowski, MC;
Indirizzi:
Univ Penn, Dept Chem, Roy & Diana Labs, Philadelphia, PA 19104 USA Univ Penn Philadelphia PA USA 19104 iana Labs, Philadelphia, PA 19104 USA
Titolo Testata:
ORGANIC LETTERS
fascicolo: 8, volume: 3, anno: 2001,
pagine: 1137 - 1140
SICI:
1523-7060(20010419)3:8<1137:EOBCRC>2.0.ZU;2-Y
Fonte:
ISI
Lingua:
ENG
Soggetto:
ASYMMETRIC-SYNTHESIS; LITHIATION-SUBSTITUTION; BINAPHTHOL DERIVATIVES; MOLECULAR RECOGNITION; OPTICAL RESOLUTION; 2,2'-DIHYDROXY-1,1'-BINAPHTHYL; EFFICIENT; PHENOLS; 1,1'-BI-2-NAPHTHOL; 1,1'-BINAPHTHYLS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
41
Recensione:
Indirizzi per estratti:
Indirizzo: Kozlowski, MC Univ Penn, Dept Chem, Roy & Diana Labs, Philadelphia, PA 19104 USA Univ Penn Philadelphia PA USA 19104 ladelphia, PA 19104 USA
Citazione:
X.L. Li et al., "Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes", ORG LETT, 3(8), 2001, pp. 1137-1140

Abstract

Chiral 1,5-diaza-cis-decalins have been examined as ligands in the enantioselective oxidative biaryl coupling of substituted 5-naphthol derivatives. Under the optimal conditions employing a 1,5-diaza cis-decalin copper(l) iodide complex with oxygen as the oxidant, rapid and highly selective couplings could be achieved (90-93% ee, 85% yield).

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 09/07/20 alle ore 14:20:31